阳离子StBAQACMs纳米球的合成及在纤维素纤维上的吸附.pdf

werewerewaswerewaterwerewithwithwithwasAbstractmonolllermeasured．matchesmonomers．ThemonomeTmonomer．WhenmodelbambooraterateDMCuniformThehasTheTheTheasanaanasanallbath．TheresultsonononononononvariousatatatTheon400nm．Surfaceandabsorbedalsoandandofcationicofofofofofcationicofofcationicofofofexcessofofcationicofammoniumammoniumammoniumammoniumamountamountamountamountabsorbedabsorbedamountabsorbedaftertofibersfiberfiberfiberfasterfiberfiberfiberanddifferentcationic300cationiccationiccationicdifferentcellulosecationicdecreasedcationiccationiccouldcationiccationiccatiohiecationicofthetextiletWOeffecttheelectronthethetothethefromfiberandandstructurediameter50nm．butdiametercationiccationicinoretreatment．Emulsifier-freeemulsionamountsurfacesizesurfaceshowedsizesurfacethethethethethetramitionthethethethetheendothermic．condmtedIdllVsurfacesurfaceleadinitiatorinincreasesisincreasedincreaseincreasedincreased．Theindicatedirreversible100nminfluemeisotherm 目录 第一章前言………………………………………………………………………………1 1。1乳液聚合…………………………………………………………………………1 1．2阳离子乳液聚合…………………………………………………………………1 1．2．1无皂乳液聚合……………………………………………………………一2 1．2．2阳离子共聚单体参与的无皂乳液聚合…………………………………．4 1．3阳离子乳胶粒在纤维表面的吸附………………………………………………5 1．3．1吸附机理…………………………………………………………………．5 1．3．2吸附动力学研究…………………………………………………………．6 第二章实验部分…………………………………………………………………………9 2．1实验材料与仪器…………………………………………………………………9 2．1．1实验材料…………………………………………………………………．9 2．1．2实验仪器…………………………………………………………………11 2．2阳离子纳米球制备……………………………………………………………一12 2．2．1阳离子纳米球合成………………………………………………………12 2．2．2单体转化率及瞬时反应速率测定………………………………………12 2．3阳离子纳米球表征……………………………………………………………．13 2．3．1扫描电子显微镜(SEM)………………………………………………13 2．3．2差示扫描量热测试(DSC)……………………………………………．13 2．3．3密度测定…………………………………………………………………13 2．3．4激光粒度测试(DLS)与粒子数(ND)计算…………………………．14 2．3．5表面电荷密度测定………………………………………………………14 2．4纳米球在纤维表面的沉积…………………．．．．………………………………．14 第三章结果与讨论……………………………………………………………………．15 3．1