《TiO2颗粒在羟基表面的沉积行为及图案化 Deposition Behavior and Patterning of TiO2 Particles on Hydroxyl Surfaces》.pdfVIP
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《TiO2颗粒在羟基表面的沉积行为及图案化 Deposition Behavior and Patterning of TiO2 Particles on Hydroxyl Surfaces》.pdf
第27卷第1期 无 机 化 学 学 报V01.27No.1
2011年1月 CHINESE
JOURNALOFINORGANICCHEMISTRY 135.140
Ti02颗粒在羟基表面的沉积行为及图案化
梁 山★,1 孙冬兰1 薛群基2
(1天津科技大学理学院,天津300457)
(2中国科学院兰州化学物理研究所固体润滑国家重点实验室,兰州730000)
摘要:比较了3种具有羟基表面Si02层的差异:紫外光照SAMs形成的羟基表面,紫外光照射前、照射后的羟基表面:用光照前
后表面的差异,结合化学浴沉积技术在单晶硅基底上制得了TiO:微图案薄膜。系统考察了光源、硅片表面性质的变化、溶液等
方面对图案生成的影响。实验表明Ti02沉积在未照区,电子和空穴动力学上的差异造成光照区表面正电荷增多,抑制了Ti02的
沉积。该方法不需要光刻胶和自组装膜作为辅助模板,具有简单廉价的特点。
关键词:图案化;光照;电子;空穴;迁移率
中图分类号:0614.41+1;0649.4文献标识码:A 文章编号:1001-4861(201I)01.0135.06
Behaviorand of Particleson
Ti02 Surfaces
Deposition Patterning Hydroxyl
LIANG
Shan。”SUN
Dong—Lan‘XUEQun-Ji2
and
(1CollegeofScience,TianjinUniversityofScience 300457,C矗伽曲
Technology,Tianjin
Abstract:Threekindsof surfacesonSi02 are surfacesareformed
hydroxyl layer compared.Thehydroxyl by
theSAMsOrthebareSiunderUV thebareSisurfacesin solution
exposing light,andtreating onlypiranha but
notunderUV thinfilmswerefabricatedontheSisubstrateswiththemethodsofUV
lisht.PatternedTi02
irradiationandchemicalbath reasonsfor formationwerediscussedin viewofthe
deposition.Thepatterns the UV
ofSiwaferandthe solution.Itwasfoundthat ontothe
Ti02
light,modifications aqueous particlesdeposited
unirradiated oftheelectronsandholescausetheholesto
regions.Differe
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