《TiS2原子薄膜厚度对其热电性质影响的理论研究 Influence of the Layer Thickness on the Thermoelectric Properties of TiS2 Nanosheets a Theoretical Study》.pdfVIP
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《TiS2原子薄膜厚度对其热电性质影响的理论研究 Influence of the Layer Thickness on the Thermoelectric Properties of TiS2 Nanosheets a Theoretical Study》.pdf
第30卷第3期 无 机 化 学 学 报 V01.30No.3
2014年3月 CHINESE OFINORGANICCHEMISTRY 506.510
JOURNAL
TiS2原子薄膜厚度对其热电性质影响的理论研究
陈昊英 张睿智★赵佩 曹利克
(西北大学物理系,西安710069)
摘要:本文采用玻尔兹曼输运方程与密度泛函计算相结合的方法,理论研究了薄膜厚度对二维TiS:原子薄膜热电性能的影响。
随着厚度的减小,薄膜的能带变平,电子有效质量增大而群速度减小,这造成了塞贝克系数的增大和电导率的减小。而且,薄膜
的功率因子及最优载流子浓度也随厚度的减小而减小。我们讨论了薄膜功率因子减小的物理机制,并与其他二维体系的实验
结果进行了比较分析。
关键词:热电材料;原子薄膜;层状材料
中图分类号:0614.41+1:0613.51文献标识码:A 文章编号:1001-4861(2014)03—0506.05
DOI:10.11862/CJIC.2014.050
Influenceofthe ThicknessontheThermoelectricof
TiS2
Layer Properties
Nanosheets:aTheoretical
Study
CHEN ZHANG
Hao—Ying Rui-Zhi+ZHAOPeiCAOLi.Ke
(DepartmentofPhysics,NorthwestUniversity,Xi’翻%710069,China)
Abstract:Withthe of dimensional
discovery nanosheetsageof interestduetotheirnovel
graphene,two great
these2D metal
sulficidnanosheetswith correlatednatureand
physics.Amongsystems,transition strong ample
variationsattractmoreandmore functionalcalculations
compositional attention.Here,byusingdensity theory
andsemi—classicBohzmann the
equations,we influenceof thicknesson
transport investigated layer
ofTiS2 bulkmaterial showssome
properties nanosheets,whose
courtpart already promising
theoreticalresultsshowthatwhenthethicknessis thanthecriticalthicknessfor
p
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