《O,O-二（2,3-二羟基丙基）二硫代磷酸对黄铜矿和方铅矿的选择性抑制》.pdfVIP

Trans. Nonferrous Met. Soc. China 23(2013) 3063−3067 Selective depression of galena and chalcopyrite by O,O-bis(2,3-dihydroxypropyl) dithiophosphate 1 1 1,2 1 1 1 Zheng-jie PIAO , De-zhou WEI , Zhi-lin LIU , Wen-gang LIU , Shu-ling GAO , Ming-yang LI 1. College of Resources and Civil Engineering, Northeastern University, Shenyang 110004, China; 2. Faculty of Resource and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China Received 28 August 2012; accepted 7 November 2012 Abstract: A novel synthesized reagent, O,O-bis(2,3-dihydroxypropyl) dithiophosphate (DHDTP), was investigated as depressant on the depression of chalcopyrite and galena, when ammonium dibutyl dithiophosphate (DDTP) was used as the collector in flotation tests. Zeta potential and adsorption measurement were performed to study the interaction between depressant and minerals. The flotation tests of two minerals show that DHDTP has slight depression on chalcopyrite in the whole pH range and strong depression on galena in the pH range of 6−10. When DHDTP dosage is increased, the recovery of galena decreases rapidly, while that of the chalcopyrite decreases slightly. The satisfied separation results of artificially mixed samples are that the copper grade and recovery rates of concentrate are 24.08% and 81%, respectively, when the pH is 6 with 278 mg/L DHDTP. Zeta potential and adsorption measurements show that DHDTP has more strongly adsorption capacity to galena than chalcopyrite. Key words: O,O-bis(2,3