原创力文档《Synthesis of ZSM-5MOR Co-crystalline Zeolite without Template and the Catalytic Application Thereof》.pdfVIP
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《Synthesis of ZSM-5MOR Co-crystalline Zeolite without Template and the Catalytic Application Thereof》.pdf
ScientificResearch
ofZSM··5／MORC
Synthesis
without andtheC
Zeolite Template atalytic
Thereof
Application
ZhangHuiming，MaGuangwei
ResearchInstitute 201208)
(Shanghai ofPetrochemicalTechnology,SINOPEC,Shanghai
Abstract：AZSM一5／MOR zeolitewas withoutthe
co-crystalline usingtemplate．The proper-
synthesized physico—chemical
tiesofthezeolitewerecharacterized andTPDandthen withthe zeolite
byXRD，FT-IR，SEM comparedco—crystalline
indicatedthat weresimilarinstructureand influences
witha results
synthesizedtemplate．Analytical they composition．The
thata valueoralowSt／A1ratiocould
valueandSi／AIratioon werestudied．Itwasfound
ofpH synthesis highpH provide
betterenvironmentfor zeolites as in for
mordenite(MOR)crystallization．Theappliedcatalystsnaphthacatalyticcracking
and showed withthetotal and
outstandingcatalytic yieldofethylenepropylene
producingethylenepropylene performance
55m％．The couldachievemostfavorable whenthe contained5m％ofMOR．
reaching process efficiency catalyst
Keywords：ZSM一5：mordenite；co—crystalline；catalyticcracking；ethylene；propylene
l Introduction economicandsocialbenefits
BoththeZSM一5zeoliteandthemordenitehavebeen Asan metho
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