聚异丁烯胺地小试合成研究.pdf

实验，证明本课题合成的聚异丁烯胺复配的汽油清净剂清净性能优于市售的多种 清净剂，是一种市场竞争力很强的绿色产品。且全部通过了中国石油环境科学研 究院汽车实验室的发动机台驾实验，完全符合 GB29592-2004 的要求。 通过对聚异丁烯胺工艺制备过程若干问题的研究，解决了产品合成过程中存 在的一些问题，实现了聚异丁烯胺产品的绿色生产。 关键词：关键词：聚异丁烯胺;环氧聚异丁烯;双氧水;环氧化;正交试验 关键词关键词：： Abstract The research is Concerning Polyisobutylene amine which is the constituent of the fourth generation gasoline detergent. It can remove deposits and coke from nozzle, intake valve and combustion chamber, and make gasoline atomization better, reducing fuel consumption and keeping the engine in a good working condition. Currently, this oil detergent is very popular, for which exce ent detergency wi have a very broad market and great vitality. This study is based on the investigation of a large number of literatures and in cooperation with the Southeast University, a green synthesis route of polyisobutylene amine with independent inte ectual property rights, has been developed. With butanol as a solvent, ethylenediamine reacted with epoxy polyisobutylene, which was given by means of epoxidation under a system of HAc-H2O2, producing polyisobutylene amine. In this paper, being based with the original technology, a number of key technology issues about producing po yisobutylene amine have been optimized as fo ows: Optimizing of the Synthesis concerning epoxy polyisobutylene technology: Some factors affecting the yield of Epoxy polyisobutene were investigated by orthogonal experiment such as concentration of hydrogen peroxide, amount of acetic acid and hydrogen peroxide etc, Accomplished good conversion of epoxy polyisobutene Under the green building-up pr