Fabrication of Titanate Barium Films by Electrophoretic Deposition Technique.pdfVIP

J．Chem．Chem．Eng．8(2014)254-259 … N 塌 FabricationofTitanateBarium FIlmSbyEIeCtrOphOretiC DepositionTechnique Maksim Zagorny，VolodymyrPidsosonnyi，AnnaIvanchuk，AlexanderZhygotskyandAndreyRagulya DepartmentofPhysicalChemistryandTechnologyofNanostructureCeramicandComposites，IvanNikitovichFrantsevichInstitute l厂0，ProblemsFOMaterialsScienceFONASFOUkraine，Kiev03680，Ukraine Received：January16 2014 ／Accepted：January28，2014 ／Published：March25，2014 Abstract：EPD (electrophoreticdeposition)techniquehasbeenshownasaneffectivemethodtoproducethinorethick layersat voltage5．100V ontoNiconductivesubstrate．Theaim ofthisstudyistousetheEPD methodtofabricatefilmsfrom suspensions BaTiO TheeffectsoftheEPD processparameterssuchasthesuspensionconcentration depositiontime，electricalfieldstrengthon thespecificEPD depositedweight，morphology particleswereused．Thesurfacem icrostructuresoftheas-depositedfilmswere investigatedbySEM (scanningelectronmicroscopy)．Ahomogeneousmicrostructurewasobtainedatappliedelectricfieldof100V andIm inofdepositiontimeatanelectrodedistanceof1．0cm ． Keywords：BaTiO3，suspension，EPD，depositiontime，viscosity，olygoperoxide 1．IntrOductiOn thicknessofseveralmicronswerepreparedbyEPD of monodisperse powders in mixture of 2一 EPD (electrophoreticdeposition)simpletechnique meth0xyethan0l—acetylacetone．Filmswereformedat hasbeenshownasaneffectivemethodtoproducethin electrodecompositionofPt／Ti／SiO2． layersontoconductivesubstrates l『一31．Itisknown High—orientedfilmBaTiO3[10]wereobtainedon thattheEPD methodisaversatilemethodtofabricate