(Co,Fe)b合金嵌锂性能研究.pdfVIP

兰兰查兰里主竺堡兰苎 一一—— Abstract the batteriesdue in small cells thestate-．of-the·-art rechargeable ion Lithium represent is and life．The workaimedtO totheir energydensitylong present voltage，high high asthecandidateanodesfor basedonmetalantimonides and newmaterials developstudy batteries． lithiumion Inthis electrochemicalof were lithium thesis，the CoSb3investigated．The properties reachabout andextraction oftheannealed 630and ioninsertion CoSb3 capacities alloy the are in first thoseof as—melted somewhat the cycle，and CoSb3 470mAhJgrespectively the and inthefirst showedthat lifecould lower(550364mAh／g cycle)．Experimentscycle was when skutterudite be afteranneal a single phase improved anodematerialscouldbe Li+reactionwiththe as electrochemicalmechanismof explained