微波催化氧化法预处理垃圾渗滤液的研究[J].pdfVIP

中国环境科学 2011,31(7) ：1166~1170 China Environmental Science 微波催化氧化法预处理垃圾渗滤液的研究 ∗ 王 杰 ,马溪平,唐凤德,杨春璐,李 悦,郭 斌 (辽宁大学环境学院,辽宁 沈阳 110036) 摘要：采用微波-活性炭-Fenton 催化氧化预处理垃圾渗滤液,研究了不同因素对垃圾渗滤液处理效果的影响.结果表明,COD 和氨氮去除率 随活性炭用量、微波辐射时间和微波功率增加而增加;随Fe2+用量和H O 用量增加,COD 和氨氮去除率先增加而后下降;随pH 值增加,氨 2 2 氮去除率显著增加,COD 去除率变化不明显.在微波功率为300W,pH 值为8,活性炭9g/L,Fe2+用量为0.02mol/L,H O 用量为7mL/L,辐射时 2 2 间6min 条件下,垃圾渗滤液中COD 和氨氮去除率分别达到68.22%和78.08%,SS 去除率达到78.55%,浑浊度去除率达到99.02%,颜色由黑 褐色去除为接近无色,BOD5/COD 由0.21 提高到0.45;研究比较了不同处理对垃圾渗滤液的处理效果.结果显示,微波催化氧化对垃圾渗滤液 中COD 和氨氮去除率明显高于其他处理. 关键词：垃圾渗滤液；微波；催化氧化；化学需氧量；氨氮 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2011)07-1166-05 * Study on pretreatment of landfill leachate by microwave-assisted catalytic oxidation process. WANG Jie , MA Xi-ping, TANG Feng-de, YANG Chun-lu, LI Yue , GUO Bin (College of Environment Sciences, Liaoning University, Shenyang 110036, China). China Environmental Science, 2011,31(7)：1166~1170 Abstract ：The microwave,activated carbon and Fenton were applied to catalyze and oxidize the landfill leachate, the effects of different influential factors on the removal of landfill leachate were investigated. The results indicated that the removal rates of COD and NH3-N enhanced with the increase in AC dosage, microwave radiation time and microwave power. However, with the increase in Fe ( Ⅱ) and H O dosage, the removal rates of COD and NH -N firstly increased 2 2 3 then decreased; with