双核开链茂铁咪唑受体的合成与阴离子识别研究有机化学.pdfVIP

DOI: 10.6023/cjoc201411030 研究论文 有机化学 Chinese Journal of Organic Chemistry ARTICLE 双核开链茂铁咪唑受体的合成与阴离子识别研究 卓继斌a 晏希泉a 王小雪a 谢莉莉a,b 袁耀锋*,a,b a ( 福州大学化学学院 福州 350116) (b 能源与环境光催化国家重点实验室 福州 350002) 摘要 通过二茂铁甲基咪唑 1 与不同的二溴代烷反应合成了一系列双核开链的茂铁咪唑受体3a～3e, 化合物3e 的晶体 结构表明分子间有着强的 C—H…F 氢键作用. 利用电化学和核磁共振氢谱考察了受体 3a～3e 对不同常见阴离子的识 别能力. 电化学滴定实验表明受体3a～3e 在乙腈溶液中均能很好地识别F－. 核磁滴定证实了受体与不同阴离子之间氢 键作用及参与类型. Job 曲线表明受体分子与阴离子间形成1 ∶1 型的配合物, 通过络合常数(Ka) 的对比表明受体3c 对氟 离子的选择性识别能力最好. 关键词 二茂铁; 开链; 咪唑鎓; 合成; 阴离子识别 Synthesis and Anion Recognition of Acyclic Ferrocene-Based Imidazole Receptors Zhuo, Jibina Yan, Xiquana Wang, Xiaoxuea Xie, Lilia Yuan, Yaofeng*,a,b a ( College of Chemistry, Fuzhou University, Fuzhou 350116) b ( State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University , Fuzhou 350002) Abstract The design and synthesis of artificial receptors capable of binding and sensing anions have been widely explored in the field of host-guest chemistry. Herein, a series of acyclic ferrocene-based imidazolium receptors 3a～3e were designed and synthesized. All the receptors were prepared by reactions of 1-(ferrocenylmethylene)imidazole 1 with corresponding dibro- mides in solvent under refluxing, followed by anion exchanges with NH PF . The structures of all the products were deter-