硅杂环戊二烯的合成及应用研究进展有机化学.pdfVIP

2011 年第 31 卷 有 机 化 学 Vol. 31, 2011 第 9 期, 1395～1405 Chinese Journal of Organic Chemistry No. 9, 1395～1405 ·综述与进展· 硅杂环戊二烯的合成及应用研究进展 马庆宇*,a 关瑞芳 a 李国忠 a 冯圣玉 b (a 济南大学材料科学与工程学院 济南 250022) (b 山东大学化学与化工学院 济南 250100) 摘要 硅杂环戊二烯是一种含硅的五元环, 是环戊二烯的类似物, 由于其具有特殊的电子结构, 在许多方面有广泛的 应用. 综述了硅杂环戊二烯化合物的合成方法, 作为光电材料、化学传感器及生物传感器等方面的应用研究进展. 最 后, 对硅杂环戊二烯的研究方向提出了展望. 关键词 硅杂环戊二烯; 聚集诱导发光; 光电材料; 化学传感器; 生物传感器 Progress in the Synthesis and Applications of Silole Compounds Ma, Qingyu*,a Guan, Ruifanga Li, Guozhonga Feng, Shengyub a ( School of Material Science and Engineering, University of Jinan, Jinan 250022) (b School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100) Abstract Siloles are a group of silicon-containing five-membered cyclic dienes. Due to their unique elec- tronic structures, they have been attracted much attention and potentially applied in many fields. In this re- view, we summarized recent progress in the synthesis of silole compounds and their applications as elec- troluminescent devices (EL), chemsensors, biosensors etc. Opposite to common phenomenon of aggrega- tion-caused quenching (ACQ) of light emission in many luminophoric molecules, silole compounds exhibit aggregation-induced emission (AIE). Enlightened by this abnormal phenomenon, the applications of silole compounds are extremely extended, including traditional EL materials, chem-, bio-sensors and many fields in progress. At last, the f