硒催化反应最新研究进展有机化学.pdfVIP

2009 年第 29 卷 有 机 化 学 Vol. 29, 2009 第 10 期, 1555～1563 Chinese Journal of Organic Chemistry No. 10, 1555～1563 ·综述与进展· 硒催化反应最新研究进展 张晓鹏* 苗江欢 孙玉标 (河南师范大学化学与环境科学学院 新乡 453007) 摘要 价廉易得的非金属硒作催化剂不但具有良好的催化活化 CO 的性能及反应过程相转移催化特性, 而且能循环使 用. 用 Se/CO 催化体系替代贵金属催化羰基化法及剧毒的光气法进行羰基化反应及用 Se/CO/H O 催化体系进行高选择 2 性的还原反应, 具有反应条件温和、原子经济性高、成本低、环境友好、路线简短、后处理方便等优点, 因而引起人 们的广泛关注. 概述了近几年来硒催化羰基化反应和硒催化选择性还原反应的最新研究进展, 并对硒催化反应的发展 趋势进行了展望. 关键词 硒催化羰基化; 硒催化还原; CO Recent Progress in Selenium-Catalyzed Reactions Zhang, Xiaopeng* Miao, Jianghuan Sun, Yubiao (College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007 ) Abstract The cheap and easily available nonmetal selenium catalyst possesses both efficiency to catalyti- cally activate carbon monoxide and the function of phase-transfer catalysis. What is more, it can be recycled. Substitution of noble metal catalyzed carbonylation and virulent phosgene methods with Se/CO catalytic system to carry out carbonylation reaction, together with applying Se/CO/H2O to carry out highly selective reduction, has many advantages such as mild reaction conditions, high atomic economy, low cost, benign environment, short synthesis approach and simple operation, which arouse broad attention. This review fo- cuses on the recent progress in the selenium-catalyzed carbonylation and the selenium-catalyzed selective reduction. Finally, the development trend