色满衍生物的不对称合成有机化学.pdfVIP

有fiL 吧?二 YOUJI 丑UAXUE， 1890 , 10 , 3.16~349 鹦贸髓移. 色;前衍生物的不对称合成 扬 -J: 英飞叶 1 、 ~t 宫31 、高济宁 (南京大学化学宗步江苏，南京， 210008) Asymmeíric Synthesis of Chroman Derivatives YANG Shi-Ying飞 YE Fei , FAN Fu-Long , GAO Ji-Yu (Department of Chemistry, Nanjing Vni;v ersity, 210008 Nanjing , Jiangsu) Abstract: The reaction of phenols with methyl vinyl ketone in tbe presence of chiral acid gave eight neW chiral chroman compoundst The enantiomeric excess of compound 1 varied from 30 to 63 %时， which depended mainly on the chiral acid used. A brief study of the scope and lim