微波辅助水热法合成BaZrO3和BaHfO3.pdfVIP

ISSN 0020-1685, Inorganic Materials, 2007, Vol. 43, No. 9, pp. 988–993. © Pleiades Publishing, Inc., 2007. Original Russian Text © V.D. Maksimov, P.E. Meskin, B.R. Churagulov, 2007, published in Neorganicheskie Materialy, 2007, Vol. 43, No. 9, pp. 1102–1108. Microwave-Assisted Hydrothermal Synthesis of Fine BaZrO and BaHfO Powders 3 3 a a, b a V. D. Maksimov , P. E. Meskin , and B. R. Churagulov a Moscow State University, Vorob’evy gory 1, Moscow, 119899 Russia b Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia e-mail: churagulov@inorg.chem.msu.ru Received December 25, 2006 Abstract—Fine BaZrO3 and BaHfO3 powders have been prepared by a microwave-assisted hydrothermal (MWHT) process. The powders have been characterized by x-ray diffraction and scanning electron microscopy, and their particle size distribution has been assessed from dynamic light scattering data. The results indicate that microwave processing during hydrothermal synthesis notably reduces the average particle size of the resulting powder and ensures a narrower particle size distribution. BaHfO particles prepared under the optimal 3 MWHT synthesis conditions are predominantly spherical in shape and uniform in size, with an average size