Investigation of Chemical Bath Deposition of ZnO Nanocrystals Thin Films Using Different ZnNO3 Concentration.pdfVIP
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Investigation of Chemical Bath Deposition of ZnO Nanocrystals Thin Films Using Different ZnNO3 Concentration.pdf
JournalofMaterialsScienceandEngineeringA2(5)(2012)442-453
… N
InvestigationofChem icalBathDepositionofZnO
NanocrystalsThinFilmSUsingDifferentZnN03
Concentration
MiguelHernfindezHern~indez,MartinLazcanoHern~ndez,JuanHermlndezTecorralco,GabrielJu~irezDiaz2
,
MelissaCMvezPortillo,SalvadorRosasCastilla,L.ChaltelLima andOscarPortilloMoreno
』.FacultaddeCienciasQuimicas,BenemitaUniversidadAut6nomadePuebla,Mdxico,Puebla,Mico
2.CIDS-ICUAP,BenemitaUniversidadAut6nomade Puebla,Mdxico
Received:February16,2012/Accepted:M arch05,2012/Published:May10,2012
Abstract:Inthiswork.thinfilmsgrowthatdifferentZnNO concentrations:0.02M ,0.03M and0.04M bychemicalbathdeposition
(CBD)as—preparedonglasssubstratesat80。C4-2。C.PatternsDiffractionx—ray(DRX)shownpeaks20 (31.72,32.769,34.36,
36.10,47.44,56.52,62.78,67.84and69.02),atconcentration0.02M showformationfromhydrozinciteZ【ns(CO3)2(0H)6】.The
opticalbandgapshiftsfrom3.8eVto3.6eV.Photoluminescence(PL)spectrashowintensityvariationofthegreenemission(GE)may
beresultedrfomvariationoftheintrinsicdefectinZnOfilms,suchzincvacancy( ),oxygenvacancy( ),andinterstitialzinc(Zni),
interstitialoxygen(Oi).ThepresenceofdefectsinoursamplesisresponsiblefortheobservedbroadvisiblePLbands;thisindicates
reductionsofoxygenvacna ciesandincreaseofoxygeninterstitials.Itcouldbebelievedthatthepresenceofdefectsinsamplesis
responsibleofrtheobservedbroadvisiblePLband.Theconcentrationincreasedthevisibledefectluminescence.whichmightbedueto
improvementtosamplestoichiometric.Thepresenceofbothgreenemission(GE)andyellowemission(YE)canbesccnthroughthe
deconvolutionofthedefectincreasingtheconcentration.thepositionoftheGE shiftedfrom 1.96-2.45eV andtheincreaseofits
intensity.TheshiftsofthesetwovisiblePLbandsmightbeduetochanges
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