《Cu-BiVO4复合光催化剂的制备及可见光催化活性》.pdf

物理化学学报(Wuli Huaxue Xuebao) May A cta Phys. Chim. Sin., 2010, 26(5) ：1337-1342 1337 [Article] Cu/BiVO 复合光催化剂的制备及可见光催化活性 4 张爱平* 进治 ( 方工业大学理学院, 北京 100144) 摘要： 利用水热法制备了Cu 掺杂的BiVO4 复合可见光催化剂, 借助X 射线衍射 (XRD) 、X 射线光电子能谱 (XPS)、紫外 可见漫反射光谱(DRS)和扫描电子显微镜(SEM)对其进行表征. XRD 分析显示所有催化剂都呈现单 斜结构. XPS 结果显示掺杂元素均以其稳定氧化态形式存在于催化剂表面. DRS 谱中掺杂样品的吸收边比纯 BiVO 都有不同程度的红移. 以甲基橙(MO)的可见光催化降解反应为探针, 研究了催化剂的可见光催化性能. 结 4 果表明, 经Cu 掺杂改性的催化剂的催化能力比纯BiVO4 有所提高. 对其掺杂增强催化能力的可能原因进行了 讨论. 关键词： 光催化; BiVO ; 复合光催化剂; 可见光; 水热法 4 中图分类号： O649 Syntheses and Activities of Visible Light Driven Cu/BiVO4 Composite Photocatalysts ZHANG Ai Ping* ZHANG Jin Zhi (College of Sciences, North China University of Technology, Beijing 100144, P. R. China) Abstract ： Cu doped BiVO4 photocatalysts were hydrothermally synthesized and characterized by X ray diffraction (XRD), X ray photoelectron spectroscopy (XPS), UV Vis diffuse reflectance spectroscopy (DRS), and scanning electron microscopy (SEM) . XRD showed that all the photocatalysts have the same single monoclinic sheelite structure. XPS results show that Cu exists on the surface of the BiVO4 catalysts as their stable oxide cation species. An absorption edge red shift was obtained by DRS studies. The photocatalytic activity was investi