13酚类污染物与L_Cys间的作用机理与电子传递.pdfVIP

34 8 ( ) Vol. 34 No. 8 2006 8 JOURNAL OF TONGJI UNIVERSITY( NATURAL SCIENCE) Aug. 2006 L- Cys 赵国华, 李宏旭, 李明芳, 胡惠康 ( , 200092) : , L- ( L- Cys) . : L- , , ; L- , , . , , .N , H ) O , L- Cys# C H O (L- Cys) # C H O . 6 6 2 2 6 6 2 , , . : L- ; ; ; ; : O 641. 3 : A : 0253- 374X( 2006) 08- 1111- 06 Mechanism of Interaction and Electron Transfer Between Phenolic Pollutants and L2Cysteine ZHAO Guohua, LI Hongxu , LI Mingf ang , H U Huikang (Department of Chemistry, Tongji University, Shanghai 200092, China) Abstract: The mechanism of interaction between L2Cysteine an phenolic pollutants was investigate on the basis of cyclic voltammetry an the UV2Vis spectrophotometry metho s. Results show that L2Cysteine immobilize onto Au electro e with or erly arrange monolayer membrane can facilitate electrons transfer an electrocatalyze the re ox of the three ihy ric phenols but affect the re ox of the three ihy ric phenols an electrons transfer when isperse in aqueous solution an presente in free an isor erly structure. Further research in icates that no strong chemical action occurs between L2Cysteine an ihy ric phenols, nor oes cleavage of ol chemical bon s or formation of new bon s. L2Cysteine an ihy ric phenols can form L2Cys# C H O or ( L2Cys) # C H O through hy rogen2 6 6 2 2 6 6 2 bon ing association. The ifference in bin ing number results in ifferent electrochemical activity an behavior, an also lea s to ifferent