超声波辅助稠油层内催化水热裂解实验研究.pdfVIP

第39卷 第8期 燃摇 料摇 化摇 学摇 学摇 报 Vol.39 No.8 2011年8月 Journal of Fuel Chemistry and Technology Aug. 2011 文章编号:0253鄄2409(2011)08鄄0606鄄05 超声波辅助稠油层内催化水热裂解实验研究 许洪星,蒲春生 (中国石油大学(华东) 石油工程学院,山东 青岛摇 266555) 摘摇 要:将超声波应用到稠油催化水热裂解实验中,研究了超声波辅助催化水热裂解对胜利油田孤东稠油物化性质的影响。 结果表明,超声波辅助作用下稠油的降黏率达到86.2%,与催化水热裂解相比,稠油的平均相对分子质量进一步减小,饱和烃 和芳香烃组分含量增加,胶质和沥青质组分含量减少,稠油组分的氢碳原子比增加,杂原子含量减小。 动态模拟实验中超声 波辅助层内催化水热裂解效果显著,稠油采收率达到53.91%,降黏率达到80.5%。 由此表明,超声波辅助催化水热裂解具有 可行性,超声波与催化剂协同作用促进了水热裂解反应,一定程度上改善了稠油的品质。 关键词:稠油;水热裂解;超声波;催化剂;降黏 中图分类号:TE357.9摇 摇 文献标识码:A Experimental study of heavy oil underground aquathermolysis using catalyst and ultrasonic XU Hong鄄xing,PU Chun鄄sheng (School of Petroleum Engineering,China University of Petroleum(East China),Qingdao摇 266555,China) Abstract:Ultrasonic wasapplied to assist the catalytic aquathermolysisreaction of heavy oil,and the effect of catalyst and ultrasonic on the physical and chemical properties of Shengli Gudong heavy oil was investigated. Compared to catalytic aquathermolysis reaction, the results of ultrasonic assisted catalytic aquathermolysis indicate that the viscosity of heavy oil isreduced by 86.2%,and the composite technology can further decrease the average molecular weight of heavy oil,increase the saturate and aromatic contents,decrease the resin and asphaltene contents,improve the mol ratio of n / n ,and decrease the heteroatoms content of heavy oil. The H C results of dynamic simulation experiments show that in鄄situ ultrasonic assisted catalytic aquathermolysis exhibits good performance with the53.91% heavy oilrecovery and80.5% viscosityreduction. The experimentalresults prove that the combination of ultrasonic and catalyst hasa