合金元素对Sn_Zn基无铅钎料高温抗氧化性影响.pdfVIP

第 11 期 电 子 元 件 与 材 料 Vol.23 No. 11 2004 年11 月 ELECTRONIC COMPONENTS MATERIALS Nov. 2004 研究与试制 R D 合金元素对Sn-Zn 基无铅钎料高温抗氧化性的影响 任晓雪，李 明，毛大立 （上海交通大学材料科学与工程学院高温材料及高温测试教育部重点实验室，上海 200030） 摘要:研究了不同微量合金元素对 Sn-Zn 基无铅钎料高温抗氧化性的影响。钎料在液态下的表面颜色变化以及热 重分析表明，Al 、Cr 能明显改善Sn-Zn 基钎料的抗氧化性能。通过俄歇能谱深度剖析和X 射线衍射分析探讨了合金元 素的抗氧化机理：Al 和 Cr 在钎料表面或亚表面富集，形成“阻挡层”，抑制了钎料的氧化。比较了合金元素对 Sn-Zn 基钎料润湿性能的影响，结果表明Al 的加入不利于钎料的铺展。通过实验得出结论：Cr 是一种比Al 更具有吸引力的 Sn-Zn 基钎料的高温抗氧化合金元素。 关键词:金属材料；无铅钎料；Sn-Zn ；合金元素；抗氧化性；润湿性 中图分类号: TN604 文献标识码:A 文章编号:1001-2028 （2004 ）11-0040-05 Effect of Alloying Elements on the High-temperature Oxidation Resistance of Sn-Zn Based Lead-free Solder REN Xiao-xue, LI Ming, MAO Da-li (Key Laboratory for High Temperature Materials Tests of the Ministry of Education, School of Materials Science and Engineering, Shanghai Jiao Tong University Shanghai 200030, China) Abstract: The effect of different alloying elements on the oxidation resistance of Sn-Zn based lead-free solder at high-temperature was studied. The results of changes of solders’surface color at high temperature and TGA show that adding Al and Cr can significantly improve the oxidation resistance of Sn-Zn based Lead-free solder. The anti-oxidation mechanisms of different alloying elements were further investigated by means of AES and XRD. Al and Cr are concentrated at the surface or subsurface of the solder and form a oxidation barrier, consequently protect the solders from further oxidation. The effect of various alloying elements on the wettability of Sn-Zn solder was discussed and its results indi