molecular photochemistry - how to strongstudystrong mechanisms of.pptVIP

下载本文档

55
0
约 54页
2016-03-05 发布于广东
举报
版权申诉

molecular photochemistry - how to strongstudystrong mechanisms of.ppt

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
7、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

molecular photochemistry - how to strongstudystrong mechanisms of

2-naphtol in NaOH Tabela 3. pKa values in the ground and lowest exited S1 and T1 states for organic compounds Compound pKa (S0) pKa*(S1) pKa*(T1) 1-Naphtol 9.2 2,0 - 2-Naphtol 9.5 2,8-3,1 7,7-8,1 1-Naphtoic acid 3.7 10-12 3,8-4,6 Acridine cation 5.5 10,6 5,6 2-Naphtylamine cation 4.1 -2 3,1-3,3 How to Utilize the Energy Content? If excited states channel their energy into specific bonds, then photochemistry can occur. If scavengers or quenchers can find the excited state or free radical in time, then the electronic or chemical energy can be captured by the, ordinarily, stable scavenger or quencher. Jablonski diagram Alexander Jab?oński (1898-1980) before 1939 University of Warsaw, Institute of Experimental Physics 1943-1945 Edinburgh Medical School 1946-1980 Copernicus University in Toruń about 70 scientific papers on atomic and molecular spectroscopy A. Jab?oński Nature 1933, 839 S1 excited singlet state S1 Jab?onski - diagram IC T1 ISC phosphorescence excited triplet state ISC T1 radiationless deactivation heat S0 singlet ground state S0 fluorescence Radiationless TransitionsShowing Nuclear Contributions “Stokes” shiftAbsorption vs Emission ? ? E = hc / ? In most of photochemical reactions of organic compounds only the lowest excited states (S1 and T1) are reactive states (rapid radiationless conversion to S1 or T1) Exceptions: emission from S2 excited singlets for azulene, thioketones Kasha’s rule Energy Gap Law The rate of radiationless transitions goes as the exponential of the energy gap between the 0-0 vibronic levels of the two electronically excited states. ?the smaller the energy gap the bigger the rate” A*(S1) + Q ? A(S0) + Q* A(S1)* + Q ? ( A?+...Q??) ? A(S0) + Q ? ( A??...Q?+) ? A(S0) + Q Processes from S1 state: - fluorescence (F) - internal conversion (IC) - intersystem crossing (ISC) S1 ? T1 - chemical reaction (RS) - quenching (+Q): - phosphorescence (P) - intersystem crossing (ISC