New technology for recycling materials from oily cold rolling mill sludge.pdfVIP

InternationalJournalolM inerals，M etallurgyandM aterials V olum e20，N um ber 12，D ecem ber 2013，Page J J DOI：10．1OO7／s12613—013—0847·8 New technologyforrecyclingmaterialsfrom oilycoldrollingm illsludge BoLiu，Shen—genZhang，Jian-junTianIDe—anPan}LingMeng，and}rangLiu InstituteforAdvancedMaterialsandTechnology，UniversityofScienceandTechnologyBeijing，Beijing100083China ， (Received：1June2013；revised：10August2013；accepted：13August2013) Abstract：Oilycoldrollingmill(cRM)sludgeisoneofmetallurgicalindustrysolidwastes．Therecycleofthese wastescan not only protectthe environmentbut also permittheirreutilization． In thisresearch a new processof ， “hydrometallurgicaltreatment+ hydrothermalsynthesis”wasinvestigatedforthecombinedrecoveryofironandorganic materialsfrom oilyCRM sludge．Hydrometallurgicaltreatment，mainlyincludingacid leaching centrifugalseparation， ， neutralizationreaction，oxidizing，andpreparationofhydrothermalreactionprecursor，was firstutilizedofrprocessingthe sludge．Then，micaceousironoxide(MIO)pigmentpowderswerepreparedthroughhydrothermalreactionoftheobtained precursorin alkalinemedia．Theseparatedorganicmaterialscanbeusedofrrue1orchemicalfeedstock．Thequalityof thepreparedMIOpigmentsisinaccordancewiththestandardsofMIOpigmentsofrpaints(ISO10601．2007)．Thisclean， effective，andeconomicaltechnologyoffersanew waytorecycleoilyCRM sludge． Keywords：coldrollingmills；sludgedisposal；hydrometallurgy；hydrothermalsynthesis；recycling，wasteutilization 1．Introduction sultin increased emission ofvolatileorganiccompounds Oilycoldrollingmill(CRM)sludge，akindofsteel includingdioxinsbutalsol