基于赤铁矿载氧体的串行流化床煤化学链燃烧试验.pdfVIP

第 30 卷 第 17 期 中 国 电 机 工 程 学 报 Vol.30 No.17 Jun.15, 2010 2010 年 6 月 15 日 Proceedings of the CSEE ©2010 Chin.Soc.for Elec.Eng. 51 0258-8013 (2010) 17-0051-06 TQ 546 A 470 10 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 基于赤铁矿载氧体的 串行流化床煤化学链燃烧试验 顾海明，吴家桦，郝建刚，沈来宏，肖军 ( 东南大学热能工程研究所，江苏省 南京市 210096) Experiments on Chemical Looping Combustion of Coal in Interconnected Fluidized Bed Using Hematite as Oxygen Carrier GU Hai-ming, WU Jia-hua, HAO Jian-gang, SHEN Lai-hong, XIAO Jun (Institute of Thermal Engineering, Southeast University, Nanjing 210096, Jiangsu Province, China) ABSTRACT: A 1 kW interconnected fluidized bed reactor was 和反应活性；随着温度由 900℃升到 985℃，燃料反应器中 built and the experiments on chemical looping combustion of CO 和 CO2 浓度迅速增加，空气反应器中 CO2 浓度则呈线性 coal was performed with hematite as oxygen carrier. The 下降；较高的温度有利于提高 CO2 捕集效率。用 BET 比表 durability of the oxygen carrier was investigated and the effects 面积、扫描电子显微镜和 X-射线衍射对使用前后的载氧体 of fuel reactor temperature on the gas compositions and CO2 进行表征，结果表明：表面轻微的烧结导致使用过的载氧体 capture efficiency were discussed. The oxygen carrier exhibited 比表面积和空隙容积都有所下降；载氧体仍保持多孔结构， an excellent stability and reactivity in a continuous test of 10 h. 这有利于其与气体之间的反应。由于喷动床高速射流的存 CO2 and CO concentration in fuel reactor increased remarkably 在，载氧体颗粒之间没有团聚现象。该种赤铁矿是实现煤化 with increasing temperature from 900 ℃ to 985 ℃, whereas 学链燃烧比较理想的载氧体。 CO2 concentration in air reactor dropped linearly. A higher fuel 关键词：化学链燃烧；串行流化床；煤；载氧体；赤铁矿 reactor temperature would contribute to improving