SO2对于铁基硫酸盐的NH3选择性还原NO催化活性的影响.pdfVIP

第 31 卷 第 23 期 中 国 电 机 工 程 学 报 Vol.31 No.23 Aug.15, 2011 2011 年 8 月 15 日 Proceedings of the CSEE ©2011 Chin.Soc.for Elec.Eng. 27 文章编号：0258-8013 (2011) 23-0027-07 中图分类号：X 511 文献标志码：A 学科分类号：470·20 SO 对于铁基硫酸盐的NH 选择性还原NO 2 3 催化活性的影响 赵宇峰，赵博，禚玉群，陈昌和，徐旭常 (清华大学热科学与动力工程教育部重点实验室，北京市 海淀区 100084) Influences of SO on the Catalytic Effect for Selective Catalytic Reduction of 2 NO by NH3 Over Iron-based Sulfates ZHAO Yufeng, ZHAO Bo, ZHUO Yuqun, CHEN Changhe, XU Xuchang (Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Tsinghua University, Haidian District, Beijing 100084, China) ABSTRACT : The effect of SO2 on the catalytic effect of 面的 Brφnsted 酸性位，促进了 NH3 的吸附，有利于NH3 与 iron-based sulfates prepared from FeSO ·7H O in NO NO 的反应，从而体现出较强的脱硝活性。考虑到脱硝活性 4 2 reduction by NH3 under 300~500 ℃ was investigated in this 以及 NH3 选择性的情况，选取 350 ℃为主要反应温度比较 research. The catalytic activity, the selectivity of NH3 and NH3 合适。 adsorption were studied using a fixed-bed reactor and in-situ 关键词：铁基硫酸盐；选择性催化还原；NH ；SO ；氨吸附 3 2 diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) over the iron-based sulfates. The experimental results 0 引言 suggest that, SO2 increases the reactivity of iron-based sulfates 燃煤发电是中国电力的主要生产方式，火