a series of chiral cyanide-bridged fe–cu complexes synthesis, crystal structures and magnetic properties:铜配合物的合成、晶体结构和磁性能的一系列手性氰桥铁-铜配合物.pdfVIP
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a series of chiral cyanide-bridged fe–cu complexes synthesis, crystal structures and magnetic properties:铜配合物的合成、晶体结构和磁性能的一系列手性氰桥铁-铜配合物
Polyhedron 100 (2015) 36–42
Contents lists available at ScienceDirect
Polyhedron
journal homepage: www.else /locate/poly
A series of chiral cyanide-bridged Fe–Cu complexes: Synthesis, crystal
structures and magnetic properties
Daopeng Zhang ⇑, Hongyan Zhang
College of Chemical Engineering, Shandong University of Technology, Zibo 255049, China
a r t i c l e i n f o a b s t r a c t
Article history: Four trans-dicyanideiron(III)-containing building blocks and two chiral copper(II) compounds
Received 28 May 2015 have been employed to assemble cyanide-bridged heterometallic complexes, resulting in six chiral
Accepted 8 July 2015 cyanide-bridged Fe(III)–Cu(II) complexes, {[Cu(S,S/R,R-Chxn) Fe(bpb)(CN) ]ClO } xCH OHy H O
2 2 4 2 3 2
Available online 17 July 2015
(1, 2), {[Cu(S,S/R/R-Chxn) Fe(bpClb)(CN) ][Fe(bpClb)(CN) ]}xCH OHy H O (3, 4 ), {[Cu(R/R-Chxn)
2 2 2 3 2 2
Fe(bpdmb)(CN) ][Fe(bpdmb)(CN) ]}4CH OH (5) and {[Cu(R/R-Chxn) ][Fe(bpdBrb)(CN) ] }4CH OH (6)
2 2 3
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