粒径可控金红石型纳米二氧化钛的制备和表征_蒋银花.pdfVIP

第 16 卷第6 期 2006 年6 月 Vol. 16 No. 6 The Chinese Journal of Nonferrous Metals Jun. 2006 : 1004 0609(2006) 06 1058 06 ① 蒋银花, 殷恒波, 邱凤仙, 姜廷顺, 凌 祺, 曹 阳 ( 江苏大学化学化工学院, 镇江212013) : 以成本低廉的偏钛酸为起始反应物, 含羧 或羟 的有机化合物为修饰剂, 采用水热合成法进行了纳 米金红石型二氧化钛的合成研究, 利用 XRD 和 TEM 等对制得的纳米二氧化钛进行表征。结果表明: 含羧 或羟 的有机化合物在修饰剂条件下都制得了纳米金红石型二氧化钛, 且修饰剂的加入抑制了棒状纳米二氧化钛的颗 粒大小, 其中修饰剂的空间位阻效应在控制合成小尺寸二氧化钛纳米棒中起主要作用, 且修饰剂的羟 和羧 的 络合作用对颗粒的生长也起到抑制作用。 偏钛酸; 粒径可控金红石型TiO ; 有机修饰剂 : 2 : TQ 134. 435 : Preparation and characterization of size-controlled rutile TiO2 nanoparticles JI NG Yin-hua, YIN Heng-bo, QIU Feng-xian, JI NG T ing-shun, LING Qi, C O Yang ( Faculty of Chemistry and Chemical Engineering, Zhenjiang 212013, China) The size-controlled hydrothermal synthesis of phase-pure rutile TiO nanoparticles was carried out using Abstract: 2 low cost metatitanic acid and hydroxyl and carboxyl group-containing organic compounds as starting material and modifiers, respectively. The specimens were characterized by X- ray diffractometry ( XRD) and transmission electron microscopy ( TEM) . T he results show that the phase-pure rutile T iO is synthesized by the hydroxyl and carboxyl 2 group-containing modifiers, and the average length and diameter of prepared rod-like rutile TiO nanoparticles de-