Effect of manganese on the catalytic performance of an iron-manganese bimetallic catalyst for light olefin synthesis.pdfVIP
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Effect of manganese on the catalytic performance of an iron-manganese bimetallic catalyst for light olefin synthesis.pdf
Availableonlineatwww.
’:三,ScienceDirect .JeC
Ⅵ“nⅣ.elsevier.cornj/ournals/
journal-of-energy-chemistry/2095-4956
JournalofEnergyChemistry22(2013)624-632 www.elesvier.com/locatej/ngc
Effectofmanganeseonthecatalyticperformanceofaniron—manganese
bimetalliccatalystforlightolefinsynthesis
一
TingzhenLi,b,一 HulinWang , YongYang , HongweiXiang斛, YongwangLi
,
a.StateKeyLaboratoryofCoalConversion,InstituteofCoalChemistry,ChineseAcademyofSciences,Taiyuan030001,Shanxi,China;
hCollegeofChemistryandEnvironmentalEngineering,ChongqingThreeGorgesUniversity,Chongqing404000,China;
c.KyeLaboratoryofEnergyThermalConversionandControlofMinistryofEducation,SoutheastUnivemi~Nanjing21009~Jiangsu,China
【ManuscriptreceivedA l6,2013;revisedJune20,2013】
Abstract
A systematicstudywascarriedouttoinvestigatethepromotioneffectofmanganeseontheperformanceofacoprecipitatediron—mangnaese
bimetalliccatalystforthelightolefinssynthesisfrom syngas.ThecatalystsampleswerecharacterizedbyN2physisorption,transmis—
sionelectronmicroscopy(TEM),X—rayphotoelectronspecrtoscopy(XPS),powderX—raydiffraction(XRD),Mrssbauerspectroscopy,H2一
differentialthermogravimetricanalysis(H2一DTG),CO reduction(CO—TPR)nadC02temperature-programmeddes—
o~tion(C02一TPD).TheFischer.n.0pschsynthesis(FTS)performanceofthecatalystwasmeasuredat1.5MPa,250。Candsyngaswith
H2/CO ratioof2.0.Thechraacterizationresultsindicatedthattheaddit
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