抑尘剂的制备与研究精要.docVIP

毕 业 论 文 题 目： 氧化淀粉接枝AA-AM抑尘剂的合成与应用研究 学 院： 化学与材料工程学院 专 业： 高分子材料与工程 姓 名： 学 号： 指导老师： 完成时间： 2015年5月15日   摘要 随着工业的迅速发展，粉尘污染对人类和环境的危害日益突出,化学抑尘是众多的抑尘方法中认为最高效的方法之一。本篇论文研制的化学抑尘剂氧化淀粉接枝AA-AM化学抑尘剂,它的抑尘机理是利用粘接性能使粉尘的表面固结，从而抑制扬尘；利用吸水保水的性能使粉尘保持润湿。本篇论文采溶液聚合的方法分三步法合成：淀粉氧化、氧化淀粉糊化、糊化淀粉接枝。通过初步的实验研究得到的配方如下：AA与AM质量比为3:2；引发剂过硫酸铵占单体总量的0.6%；交联剂N，N0.1%；AA与氢氧化钠中和，中和度为50％；接枝温度为60℃，接枝反应5h。实验证明它水溶性良好。 本篇论文利用电厂的粉煤灰作为测试对象，喷洒后测试其保水性能，以及固结层强度性能。结果如下:当抑尘剂与水的配比达到1:50时，粉煤灰堆的吸水保水性能良好；当抑尘剂与水的配比1:25时，粉煤灰堆固结强度良好。综合以上本产品是一种具有性能优良的化学抑尘剂，深入的研究并改进后将会很好的应用前途。 关键词: 溶液聚合, 接枝共聚, 氧化淀粉, 交联 Abstract With the rapid development of industry, dust pollution hazards to humans and the environment have become increasingly prominent, chemical dust suppression dust suppression is one of the many methods and the most efficient way. This paper developed a chemical dust suppressants oxidized starch graft AA-AM chemical dust suppressants, its dust suppression mechanism is the use of dust adhesion to the surface of the consolidation, thereby inhibiting dust; the use of water-absorbing properties so that dust holding wetted. This paper adopted a three-step solution polymerization method of synthesis: starch oxide, gelatinized starch, gelatinized starch graft. Preliminary experimental study was formulated as follows: acrylic acid and acrylic mass ratio of 3: 2; initiator, ammonium persulfate 0.6% of the total monomers; crosslinking agent N, N- methylene-bis-acrylamide single account body weight of 0.1%; AA with sodium hydroxide and neutralization degree of 50%; grafting temperature is 60 ℃, grafting 5h. It proved a good water-soluble. ????This paper plants using fly ash as a test object, and after spraying test the water conservation, as well as the consolidation layer strength applica