Anaerobic degradation of adsorbable organic halides (AOX) from pulp and paper industry wastewater.docVIP

Anaerobic degradation of adsorbable organic halides (AOX) from pulp and paper industry wastewater 纸浆造纸工业废水中吸附性有机卤化物的厌氧降解 Abstract 摘要 Adsorbable organic halides (AOX) are generated in the pulp and paper industry during the bleaching process. These compounds are formed as a result of reaction between residual lignin from wood fibers and chlorine/chlorine compounds used for bleaching.Many of these compounds are recalcitrant and have long half-life periods. Some of them show a tendency to bio-accumulate while some are proven carcinogens and mutagens. Hence, it is necessary to remove or degrade these compounds from wastewater. 在纸浆造纸工业，吸附性有机卤化物在漂白过程中产生。在漂白过程中使用纤维中残留的木质素与含氯化合物相互反应，形成吸附性有机卤化物，大部分的卤化物都是难降解的且有很长的半衰期，当一些卤化物被证明有致癌、致突变时，其中的一些卤化物表现出生物富集的趋势。因此，对废水中的这些化合物的去除和降解是很有必要的。 Physical, chemical and electrochemical methods reported to remove AOX compounds are not economically viable. Different types of aerobic, anaerobic and combined biological treatment processes have been developed for treatment of pulp and paper industry wastewater. Maximum dechlorination is found to occur under anaerobic conditions. However, as these processes are designed specifically for reducing COD and BOD of wastewater, they do not ensure complete removal of AOX. This paper reviews the anaerobic biological treatments developed for pulp and paper industry wastewater and also reviews the specific micro-organisms reported to degrade AOX compounds under anaerobic conditions, their nutritional and biochemical requirements. It is imperative to consider these specific micro-organisms while designing an anaerobic treatment for efficient removal of AOX. 在去除吸附性有机卤化物中，物理、化学和电化学方法在经济上不可行，在造纸工业废水处理中，不同类型的好氧、厌氧生物处理工艺及结合生物处理工艺已经得到运行，证明在厌氧条件下脱氯效果最好，然而，这些过程都是专为降低废水中的COD和BOD，不能确保完全去除吸附性有机卤化物。本文综述了厌氧生物处理纸浆造纸废水和特定微生物降解AOX化合物在厌氧条件下，其营养和生化的要求，这是考虑这些特定的微生物而有效地去除AOX厌氧处理设计势在必行。 Keywords: Adsorbable organic halides; Pulp and paper industry; Anaerobic degradation; Organochlorine degradation; Wastewater treatment