联吡啶类电致变色材料的合成及器件(硕士学位论文) - 副本.docVIP

分类号：O69 密 级：公开 档案号：2014-06-09-081704-24-012 学 号：1111091012  含联吡啶类电致变色材料的制备 与全固态器件性能研究 Master Candidate: Supervisor: Professor Major: Applied Chemistry June,2014 摘 要 联吡啶类有机电致变色材料因其丰富的色彩和较快的颜色转换速度成为当前绿色光电材料的研究热点。本文以4,4’-联吡啶和取代三联吡啶为前驱体，合成了4类不同类型的联吡啶化合物，共计13个目标化合物，并对其结构做了表征。运用紫外和电化学分析了各化合物的光电性质和电致变色机理。结果表明：小分子紫精是通过氧化还原使分子结构在苯式和醌式间相互转换实现电致变色的，而联吡啶金属配合物的电致变色则是通过金属离子与配体间电荷迁移来实现的。 分别通过旋转涂布和电化学沉积法在ITO导电玻璃上制备了联吡啶化合物的电致变色薄膜，并对其光电性能做了测试。以LiClO4-PMMA/PEO聚合物电解质为PE层制作了基于ITO玻璃的全固态电致变色器件，对器件的性能进行了测试。结果表明：以4,4’-双三苯胺紫精为EC材料的电致变色能够在0~-0.8V之间实现由无色到蓝绿色的可逆变化；以联吡啶的Fe(Ⅱ)配合物和Ru(Ⅱ)配合物为EC材料的电致变色器件在0~3V之间分别能够实现由紫色到蓝绿色和由橙红色到绿色的可逆变化。所有器件在不超过3 V的驱动电压下，可以在着色和褪色两种状态下稳定可逆变化，着色/褪色时间响应较快，开路记忆时间长达300min，说明本文所制备的器件均具有优良的电致变色性能，有望制作实用的电致变色器件。 关键词：联吡啶 紫精 电致变色 循环伏安 固体电解质 全固态电致变色器件 Abstract Organic electrochromic materials with bipyridine group are the hot issue of focus in green photovoltaic materials due to its rich colors and fast color conversion speed. In this paper, four kinds of different bipyridine-based compounds, totaling 13 target compounds, were synthesized using 4,4-bipyridine and substituted terpyridine as precursors, and their structures were characterized. The optical performance and electrochromic mechanism of the compounds were tested via UV-visible spectrophotometry and cyclic voltammetry. The results showed that: the small molecule viologen achieves electrochromic when its molecule structure change between benzene and quinone by redox, while the electrochromic of bipyridine metal complexes are achieved through charge transferring between the metal ions and the ligands. Electrochromic films of bipyridine compounds were prepared by spin coating and electrochemical deposition on ITO conductive glass respectively, and their optical performance were tested. All-solid-state electrochromic devices based on conductive ITO glass were fabricated using LiClO4-PMMA/PEO polymer electrolyte as PE layer, and the performances of the devic