年产六万吨聚苯乙烯聚合工段工艺设计讲义.docVIP

设计说明 可发性聚苯乙烯（Expandable PolyStyreneEPS）通称聚苯乙烯和苯乙烯系共聚物，是一种树脂与物理性发泡剂和其它添加剂的混合物。最常见的可发性聚苯乙烯是含有作为发泡剂的戊烷的透明PS粒料。esign notes Expandable Polystyrene (Expandable PolyStyrene, referred to as EPS) commonly known as the Department of polystyrene and styrene copolymer is a kind of mixture with resin the physical blowing agent and other additives mixture. The most common is to be made of polystyrene with n-pentane as a blowing agent aggregates of transparent PS. The design is about of polystyrene polymerization process section that the annual production capacity is 60,000 tons, The reaction mechanism is free radical polymerization, suspension polymerization process used styrene as monomer, water suspension medium done using one-step production of low-temperature suspension polymerization process. This method is adding styrene monomer, initiator, dispersing agent, water, blowing agent and other auxiliaries to reactor, the polymer containing a foaming agent, after the resin particles by washing, centrifugal separation and drying, the system may be made of polystyrene beads products; mainly contrapose the polymerization reactor carried out for material balance, heat balance, in this based on the analysis process to select out of the process equipment and calculate and draw the flow chart with control points. And the preparation of the design specifications and calculations of the book. Key Words：Expandable PolyStyrene Suspension Technique Craft calculation Technological design 1 1.1概述 1 1.1.1聚苯乙烯简介 1 1.1.2聚苯乙烯的基本物性 1 1.1.3国内外的现状及发展前景 2 1.2设计依据 2 1.3指导思想 2 1.4厂址的选择 3 1.5节能与环境保护 3 1.5.1节能 3 1.5.2环境保护 3 1.6安全防火 3 1.6.1消防设施 3 1.6.2灭火程序 4 2 工艺论证 5 2.1工艺原理 5 2.1.1生产方案 5 2.1.2 工艺路线 5 2.1.3工艺流程 5 2.1.4反应原理[9] 5 2.2聚苯乙烯的生产技术 6 2.3发泡聚苯乙烯技术工艺比较 6 2.3.1塔式本体聚合技术 6 2.3.2添加少量溶剂的单釜连续本体聚合技术 7 2.3.3苯乙烯的悬浮聚合 7 2.3.4苯乙烯种子法悬浮聚合 7 2.4发泡聚苯乙烯生产工艺 8 2.4.1一步法聚合工艺 8 2.4.2二步法聚合工艺 8 2.4.3一步法工艺与二步法工艺的比较 8 2.5可发性聚苯乙烯基本性能 9 2.5.1力学性能 9 2.5.2绝热性能 9 2.5.3化学性能 9 3 聚合工段工艺和生产流程 11 3.1聚合工段工艺过程叙述 11 3.2生产流程 11