CaZnAl类水滑石的制备及其对磷的吸附研究 毕业论文.docVIP

摘 要 吸附剂[1-2]。关键词：类水滑石 吸附 磷溶液 影响因素Abstract Hydrotalcite (HT) is a layered structure of the nano particles， with interlayer anionic exchange ability，memory function of composite oxide ，large specific surface area， the synthesis is simple，rich sources，Low price， to various heavy metal ions， organic anion， inorganic anions and so has strong adsorption capacity， can be used as anion selective adsorption agent. Hydrotalcite calcined products ( HTC ) has a unique memory effect， greater anion adsorption capacity and greater specific surface characteristics. It is also a kind of important anion selective adsorption agent. This paper adopts the low supersaturation coprecipitation synthesis of CaZnAl hydrotalcite， comparison of hydrotalcite and its calcined material on phosphorus adsorption， investigation of baking temperature on Adsorption Properties of hydrotalcite， examines different preparation temperature， different preparation time and adsorption time， temperature， pH value on phosphorus adsorption property the effect of. The experimental results show that: Calcined hydrotalcite-like compounds on phosphorus solution has obvious effect of adsorption， adsorption effect is best is the Hydrotalcite of aging 6h in 70 degree Centigrade，then roasting 300 degree Centigrade，the adsorbed solution pH value is 5，in 50 degree Centigrade adsorbent 3h ，he phosphate solution adsorption rate99%. Keywords: Hydrotalcite preparation adsorption phosphate solution Influence factors  第一章 前言 水滑石（Hydrotalcite，简称HT）是一种天然的镁、铝羟基碳酸化合物，理想分子式为Mg6Al2(OH)16CO3·3H2O，它具有水镁石型的正八面体结构，结构的中心为 Mg2+、Al3+，定点为OH-，相邻的八面体通过共边形成层，层与层间对顶地叠在一起，层间通过氢键缔合[3]。由于Mg2+被半径相近的Al3+取代，导致土板层上正电荷的积累，而这些正电荷可被位于层间的CO32-平衡，层间的其余空间则以结晶的形式被填充。这样便形成了水滑石层状结构。若水滑石层板上的Mg2+、Al3+离子分别被其它具有价态相同、半径相近的金属离子（如Zn2+、Ni2+、Cu2+、Co2+、Fe3+、Ce3+等）所取代，或者当层间的CO32-离子被一些无机或有机阴离子（如：NO3 –、SO42-、 V10O286-、 Mo7O246-等 ）所取代时，就会形成一系列不同种类、不同性质的类水滑石化合物(Hydrotalcite-Like-Compounds，简称HTLcs)，一般可用通式[M1-x2+Mx3+(OH)2