金粗糙表面原子水平的STM研究(英文).pdfVIP

第 1 期 蔡雄伟等: 金粗糙表面原子水平的 STM 研究 ·25 · layer atom s of po lycrystalline A u p resen t a largely differen t su rface structu re from the bu lk. To ou r know ledge, th is is the first STM w o rk on a po lycrystalline su rface w ith atom ic reso lu tion. It shou ld be no ted that chem ical treatm en t rather than m echan ical po lish ing is essen tial fo r the ob servation of a po lycrystalline su rface of atom ic reso lu tion. A s is expected, the rem oval of the top layers of atom s in the chem ical treatm en t is m o re natu ral and fo llow s the energetic sequence so that a fresh and stab le su rface is ob tained. In conclu sion , w e have dem on strated layer by layer cavity and thu s po rou s structu re fo r m ation of A u ( 111) su rface after a po ten tial excu rsion to the ox idation po ten tial in the p res - ence of C l . T h is po rou s structu re m ay po ssesses po ten tial and special physical and chem ical . p roperties in teresting to m any sub jects W e have also dem on strated atom ic im aging of a A u po lycrystalline su rface and qu ite differen t structu re and arrangem en t of the top layers are ob served. W e hope that th is w o rk on po lycrystalline su rface w ith atom ic reso lu tion sheds ligh t on STM studies of adso rp tion , depo sition and m any o ther sign ifican t p rocesses on p ractically . im po rtan t sub strates Ke y w o rds 　Go ld , Rough su rface, STM , A tom ic reso lu tion Re fe re nce 1　 . , . , . , . . . . , 181 ( 1987) 92 B D raw ke R Sonnesfeld J Schneir P K H ansm a S u rf ace S ci 2　 .