三种磺酰脲类除草剂在土壤中的降解及吸附特性.pdfVIP

第 32 卷第6 期 环　 境　 科　 学　 学　 报 Vol.32,No.6 2012年6月 　Acta Scientiae Circumstantiae Jun. ,2012 郭敏,单正军,石利利,等.2012.三种磺酰脲类除草剂在土壤中的降解及吸附特性[J].环境科学学报,32(6):1459-1464 Guo M,Shan Z J,Shi L L,et al. 2012.Degradation and adsorption characteristics of three sulfonylurea herbicides in different soils[J].Acta Scientiae Circumstantiae,32(6):1459-1464 三种磺酰脲类除草剂在土壤中的降解及吸附特性 ∗ 郭敏 ,单正军,石利利,宋宁慧,许静 环境保护部南京环境科学研究所,南京210042 收稿日期:2011-08-24　 　 　 修回日期:2011-09-20　 　 　 录用日期:2011-09-21 摘要:采用室内模拟试验方法,研究了氟胺磺隆、氯吡嘧磺隆和磺酰磺隆3种磺酰脲类除草剂在5种不同种类土壤(江西红壤、太湖水稻土、东 北黑土、南京黄棕壤、陕西潮土)中的降解及吸附特性.结果表明,这3种磺酰脲类除草剂在这5种不同土壤中的降解速率均比较快,且降解过 程均遵循一级动力学方程,土壤pH值是影响土壤降解速率的主要因素.3种磺酰脲类除草剂在土壤中的吸附均符合Frendlich模型,且具有较 -1 低的吸附容量.3种磺酰脲类除草剂在不同土壤中的吸附自由能变化均小于40 kJ·mol ,吸附主要以物理吸附为主,吸附常数随土壤pH值的 增大而逐渐减小. 关键词:氟胺磺隆;氯吡嘧磺隆;磺酰磺隆;土壤降解;吸附性 文章编号:0253-2468(2012)06-1459-06　 　 　 中图分类号:X53　 　 　 文献标识码:A Degradation and adsorption characteristics of three sulfonylurea herbicides in different soils ∗ GUO Min ,SHAN Zhengjun,SHI Lili,SONG Ninghui,XUJing Nanjing Institute of Environmental Science,Ministry of Environmental Protection,Nanjing210042 Received24 August2011;　 　 　 received in revised form20 September2011;　 　 　 accepted21September2011 Abstract:The degradation and adsorption of 3 sulfonylurea herbicides (triflusulfuron-methyl,halosulfuron-methyl and sulfosulfuron) in 5 typical soils were investigated under laboratory conditions with the governing factors explored. The results showed that these three sulfonylurea herbicides degraded quickly in soils and the degradation behaviors of these three sulfonylurea herbicides could be described by first-order kineticsvery well. The pH of soils wasthemainfactorcontrollingdegradationrate. Furthermore,theresultsshowedthattheadsorptionofthesethr