Ti-MOR钛硅分子筛催化甲乙酮氨氧化反应性能.pdfVIP

2013 Chinese Journal of Catalysis Vol. 34 No. 1 DOI : 10.3724/SP.J.1088.2013.20860 : 243–250 Ti-MOR , , , , , * , , 200062 : TiCl , (Ti-MOR), H O , 4 2 2 Ti-MOR (MEK) (MEKO) , Ti-MOR . , , Ti-MOR MEK MEKO 95% 99% , TS-1; , MEK MEKO Ti-MWW . : Ti-MOR ; Ti-MWW ; ; ; ; : 2012-08-31. : 2012-09-21. : 2013-01-20. *. /: (021 : pwu@ : U1162102);(2012BAE05B02); (B409). Highly efficient synthesis of methyl ethyl ketone oxime through ammoximation over Ti-MOR catalyst * DING Jianghong, XU Le, XU Hao, WU Haihong, LIU Yueming, WU Peng Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China Abstract: The liquid-phase ammoximation of methyl ethyl ketone (MEK) to methyl ethyl ketone oxime (MEKO) with ammonia and hydro- gen peroxide was conducted over MOR-type titanosilicate (Ti-MOR), which was prepared from highly dealuminated mordenite and TiCl4 vapor by a secondary method of gas-solid phase reaction. The effects of reaction parameters on this reaction were studied systematically in a bath-type reactor. Based on the optimized reaction conditions, Ti-MOR was further employed as the catalyst for the ammoximation of MEK to MEKO in a continuous slurry reactor. This catalyst exhibited good cata