黄腐酸钙镁肥中钙镁离子的测定要点解析.docVIP

黃腐酸钙镁肥中钙镁氯离子的测定 xxx1,xxx2 (1河北联合大学机械学院,2河北联合大学化工学院，唐山,063009) 摘要：根据EDTA滴定法及硝酸银滴定法原理，采用透析法对某企业生产的黄腐酸钙镁肥中钙镁氯离子的渗透前后浓度进行测定。结果表明，该黄腐酸盐中含有20.6%的钙元素、2.775%的镁元素，8.9318%的氯元素；经过在室温条件下透析48h后黄腐酸钙镁肥中含2.2%的钙元素、0.346%的镁元素、0.6035%的氯元素，经渗析后钙、镁、氯流失率分别89.32%、84.27%、93.24%。采用透析的方法使钙、镁、氯流失率较大，提出应控制一定渗透条件才能使氯离子 分离且钙、镁流失少。 关键词：黄腐酸钙镁肥；钙镁氯离子；EDTA滴定法；硝酸银滴定法；透析引言 黄腐酸一种天然生长调节剂具有较强的化学活性和生物活性，促进农作物生长提高作物抗逆性能改善作物品质、促进营养吸收利用对农药增效减毒等作用。腐酸lgKMgY＞lgKMgIn MgIn- 中夺取Mg2+，反应式如下： MgIn-+H2Y2-←→MgY2-+HIn2-+H+ （EDTA滴定Mg2+允许的最小ph值为：logαY（H）=8.63-8=0.63 9.5～10.0lgαY（H）=10.69-8=2.69 7.5～8.0） Mg2+→Mg（OH）2↓ Ca2++HIn2-=CaIn-+H+ （红色） Ca2++H2Y2-=CaY2-+2H+ 终点时：CaIn-+H2Y2-=CaY2-+HIn2-+H+ 红 蓝 1.3透析过程 用量筒量取5mL黄腐酸腐酸Determination of calcium and magnesium chloride ion in the fulvic fertilizer Tian Zeng-jie1,Sun Xiao-ran2 Mechanical Engineering College of Hebei Union University，2.Chemical Engineering College of Hebei Union University Abstract: According to the principle of EDTA titration and silver nitrate titration, dialysis method on an enterprise production of fulvic acid, calcium and magnesium fertilizer, calcium and magnesium chloride ion penetration before and after concentration were measured. The results showed that the fulvic acid salt containing 20.6% calcium, 2.775% magnesium and 8.9318% chlorine; after dialysis after 48h at room temperature fulvic acid, calcium and magnesium fertilizer containing 2.2% calcium, 0.346% of magnesium, 0.6035% elemental chlorine, calcium, magnesium, chlorine loss rate after dialysis were 89.32%, 84.27%, 93.24%.Using the method of dialysis to the calcium, magnesium, chlorine loss rate proposed should be controlled to a certain osmotic conditions in order to make the loss less chloride ion separation and calcium and magnesium. Keywords: fulvic acid, calcium and magnesium; calcium and magnesium chloride ion; of EDTA titration; silver nitrate titration; dialysis 图1 铬黑T结构式 图2透析装置示意图