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- 约 15页
- 2016-05-13 发布于新疆
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合成工艺对聚苯胺导电性能的影响
摘 要
以樟脑磺酸(CSA)为乳化剂、盐酸和樟脑磺酸(CSA)为掺杂剂、过硫酸铵为引发剂,采用乳液聚合法合成了导电聚苯胺(PAn)。研究了反应时间及苯胺、樟脑磺酸(CSA)、盐酸和过硫酸铵配比对聚苯胺电导率的影响。研究结果表明:原料量的比为苯胺∶盐酸∶樟脑磺酸(CSA) ∶过硫酸铵=1∶0.1∶1∶0.5,反应温度为8℃,反应时间为6h下,制得聚苯胺导电性最好;采用樟脑磺酸(CSA)和盐酸为掺杂剂,提高了聚苯胺的导电性。
关 键 词:聚苯胺;乳液聚合;掺杂剂;导电性;合成工艺
Abstract
The transmiting electric polyaniline was synthesized by emulsion polymerization which was carried out by using CSA as emulsifier, hydrochloric acid and CSA as doping agent, ammonium persulfate as initiatorThe influences of reaction temperature, reaction time and ratios of aniline, hlorhydric and ammonium persulfate on the conduct
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