燃煤电厂中微量元素迁移释放研究.pdfVIP

第 23 卷第 6 期 环 　境 　科 　学 　学 　报 Vol . 23 ,No . 6 2003 年 11 月 ACTA SCIENTIAE CIRCUMSTANTIAE Nov. ,2003 ( ) 文章编号 2003 　　　中图分类号 :X523 　　　文献标识码 :A 燃煤电厂中微量元素迁移释放研究 ( 中国矿业大学资源学院 ,江苏徐州 　221008) 王文峰 , 秦 　勇 , 宋党育　 摘要 :基于原煤 、飞灰及底灰的测试分析 ,对晋北一家燃煤电厂中硫等 43 种元素向环境的迁移释放作了定量研究. 结果表 明:Al 等 30 种元素基本留在固体燃煤产物中;As 等 10 种元素部分留在固体燃煤产物中,部分挥发到大气中;元素 Br 、Hg 及 硫基本挥发到大气中;各元素的挥发程度与自身的赋存状态及地球化学性质等有关. 关键词 :燃煤电厂 ;微量元素 ;燃煤产物 ;迁移释放 Study on the mobility and release of trace elements in coalf ired power plant ( WANG Wenfeng , QIN Yong , SONG Dangyu 　 College of Mineral Resources , China University of Mining and Technology , Xuzhou 　221008) Abstract :Based on the analyses of the samples of raw coal ,fly ash and bottom ash collected from a power plant from the Northern Shanxi ,China , the mobility and emission of sulfur and 42 other elements in these samples were studied quantitatively. The results indicated that :Al and 29 other elements were primarily retained in solid combustion residues ;As ,Be ,Cd ,Na ,Nb ,Ni ,P ,Pb , Sb and Se were only partially retained in solid combustion residues and partially emitted to the atmosphere ; Hg ,Br and S were primarily emitted to the atmosphere ;the volatile degree of the elements are controlled by their occurrence and geochemistry properties etc . ;the mean concentrations of S ,Hg and Be emitted form the power plant were calculated theoretically and exceed maximum limit of atmosphere environment standard ,and more attention should be paid to them. Keywords :coalfired power plant ;trace elements ;coal combustion residues ;mobility and mission 煤燃烧除产生大量 SOx 和NOx 等有害气体外 ,煤中有害微量元素也会向环境迁移转化 , 从而降低环境质量[ 1]