20110222121_林方盛_硫化镉掺杂二氧化钛纳米管的制备及光催化性能研究教程分析.doc

毕业论文 题 目硫化镉掺杂二氧化钛纳米管的制备催化性能研究 学 院 化学化工学院 专 业 应用化学 班 级 应化1104 学 生 林方盛 学 号 20110222121 指导教师 王红研 二〇一五年六月十日摘 要 近年来得到人们广泛的关注与研究。但金属掺杂可在半导体表面引入缺陷位置或改变结晶度从而影响电子与空穴的复合或拓展光的吸收波段从而提高TiO2的光催化活性。本文主要研究了硫化镉的掺杂对二氧化钛纳米管的光催化活性的影响。本次实验采用电化学阳极氧化法以在纯 Ti 片表面制备出结构整齐有序的TiO2纳米管阵列 本次实验通过各种对比得出硫化镉的掺杂在可以促进二氧化钛纳米管的光催化活性，过多的掺杂硫化镉的光腐蚀现象比较明显影响纳米管活性。 关键词：阳极氧化；TiO2纳米管；硫化镉；光催化 ABSTRACT TiO2 nanotubes because of their special photophysical and chemical properties, and high activity, good thermal stability, oxidation resistance, low cost, safe, non-toxic, no secondary pollution, harmless and non-corrosive, can be used repeatedly and other advantages, in recent years much attention and research. But its wide band gap energy gap can only be a short wavelength ultraviolet light (λ 387 nm) excitation, leading to low absorption of light quantum efficiency, thus affecting the application of TiO2. Metal-doped semiconductor surface defects can be introduced in position or change the degree of crystallinity, thus affecting the recombination of electrons and holes or expand light absorption bands, thus improving the photocatalytic activity of TiO2, thereby to improve their utilization of visible light. This paper is intended to study the impact of CdS photocatalytic activity of titanium dioxide nanotubes doped. This experiment electrochemical anodic oxidation of ethylene glycol solution of 0.5% of fluoride ions as electrolyte, at a constant voltage in pure Ti substrate surface structure orderly prepared TiO2 nanotube arrays. Reaction nanotubes were successively immersed in cadmium nitrate solution with sodium sulfide, cadmium sulfide doped to complete. By scanning electron microscopy (SEM) analysis of the crystal structure and surface morphology of TiO2 nanotubes, the results showed the prepared product anatase T