【参考】固相配位反应及配合物性质表征.docVIP

固相配位反应及配合物性质表征 摘要：本实验研究的是固相配位反应及其配合物的表征，在室温下将8-羟基喹啉与醋酸锌，按物质的量之比为2：1，在研钵中充分研磨，发生固相配位反应。混合物颜色逐渐由浅暗黄色变黄绿色，最后变为浅亮黄色。用IR、TG-DTA和XRD对产物进行表征,其测定结果表明：配合物的反应级数n=1，活化能Ea=218.75kJ/mol,频率因子k0=1.37×1012，速率系数k=5.83×10-3s-1。 关键词：8-羟基喹啉；醋酸锌；固相反应；表征 Abstract: The solid-phase reaction at room temperature was studied. The compounds were synthesized and characterized with eight -hydroxyquinoline and Zinc-accurate according to the molar ratio of 2:1 weighing. The Mixture colour gradually from dark yellow to yellow green, finally to light yellow. The products were characterized by IR, TG-DTA and XRD. Their results