吸附20110517资料.pptVIP

吸附柱的 总吸附量 出水物质浓度 ?i 累计产水量 ? 吸附能力没有得到发挥 ?厚度吸附层的吸附能力 f (x/m)x (x/m) y y ? y dy 在体积微元内，吸附量与该时刻该体积微元内的有机物浓度表现平衡关系，可以用等温吸附线来描述 在体积微元内，单位时间内从水中去除的有机物的量=单位时间内被吸附的有机物的量 在体积微元内，单位时间内从水中去除的有机物的量=单位时间内被吸附的有机物的量 假设吸附反应为一级反应，反应物有效浓度应当为（?-?e） 未知 通过搅拌吸附试验求ka 对于单位截面积的体积微元 0到y积分 ?b到?积分 上面表示式中?未知 ?e ? ?i 等温吸附线 操作线 x/m 0 ?e ? 为求? 假定单位时间内活性炭吸附的有机物量与单位时间内通过单位吸附柱截面面积的有机物量成正比 ?=?i时，该直线通过(x/m) ?i点 ?- ?e为吸附的推动力 Fro the case where the mass transfer rate is fast and the mass transfer zone is a sharp wave front, a steady-state balance around a carbon contactor reactor yields: Accumulation = inflow –outflow- amount absorbed Q= volumetric flowrate, L/h; Ce= final equilibrium concentration of absorbate, mg/L; C0= initial concentration of absorbate, mg/L; qe= adsorbent phase concentration after equilibrium, mg adsorbate/g adsrobent t= time, h; mGAC=mass of absorbent, g; The adsorbent usage rate is defined as If it is assumed that the mass of the adsorbate in the pore space is small compared to the amount adsorbed, then the term QCet can be neglected. The adsorbent usage rate is given To quantify the operational performance of GAC contactor, the following terms have been developed and are used commonly: 1. Empty-bed contact time (EBCT) EBCT= empty bed contact time, h Vb= volume of GAC in contactor, m3 Q= volumetric flowrate, m3/h Ab= cross sectional area of GAC filter bed, m2 D= length of GAC in contactor, m vf= linear approach velocity, m/h 2. Activated carbon density ?GAC= density of GAC, g/L mGAC= mass of GAC, g 3. Specific throughput, expressed as m3 of water treated per gram of carbon Specific throughput 4. Carbon usage rate (CUR), expressed as gram of carbon per m3 of water treated 5. Volume of water treated for a given EBCT, expressed in liters, L 6. Bed life, expressed in days, d CUR EXAMPLE: ESTIMATION OF ACTIVATED CARBON ADSORPTION BREAKTHROUGH TIME A fixed bed activated carbon adsorber has a fast mass transfer rate, and the mass transfer zone is essentially a sharp wavefront. Ass