纳米材料的组装汇总.pptVIP

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * SiO2纳米管 Ref. Nano Letters, 2001,1 (11), 601-603 (3) Au 纳米棒为模板 A, Au nanotubes; B, Pt nanotubes; C,D,Pd nanotubes; Ref. Younan Xia et al, Adv.Mater,2003,15(7)640 (4) Ag 纳米线为模板 a) Typical SEM image of carbon spheres; b) typical TEM image of carbon spheres; c,d) typical TEM image of Ga2O3 hollow spheres; f) SEM image of intact Ga2O3 hollow spheres 100 nm in diameter (inset: SEM image of large hollow spheres 1500 nm in diameter, which were deliberately broken by crushing in a mortar to show the hollow interior); g,h) typical TEM images of Ga2O3 hollow spheres preparedby using templating carbon spheres from sucrose rather than glucose solutions. (5) 表面层吸附模板技术（SLA）得到了单分散的Ga2O3和GaN半导体空心球 X.Sun, Y.D.Li, , Angew.Chem.Int.Ed. 2004,43,3827-3831 用碳球做模板制备GaN空心球的示意图 2. 超声化学法 N.Arul Dhas and Kenneth S.Suslick, J.Am.Chem.Soc.,2005,127,2368-2369 3. 原位-前驱物模板-界面反应法 原位前驱体模板界面反应法制备CdS 空心球的示意图 J.X.Huang,Y. xie, B. Li, et al, Adv.Mater,2000,12,808-811 4. γ射线辐照法 NiS空心球的制备示意图 Y. Hu, J. Chen, W.M. Chen, et al, Adv.Mater.,2003,15,726-729 5. 界面自组装反应法 J.C.Bao, et al, Adv.Mater.,2003,15,1832 6.1.4 存在问题与课题设计 1. 科学问题 包覆机理的研究，核材与壳材之间的界面反应及反应规律的研究。 2. 技术问题 新的制备方法的进一步探索（工业化、实用化） 寻求新的表征方法 6.2 一维纳米材料的研究(Study on 1-D Nanomaterials)6.2.1 纳米线（nanowires）的研究6.2.2 纳米管（nanotubes）的研究6.2.3 纳米棒（nanorods）的研究 1. 模板法 General scheme for the synthesis of one-dimensional nanostructures (nanowires and nanorods) by the deposition of materials into nanoporous templates. 无机纳米线的制备 6.2.1 纳米线（nanowires）的研究 SEM images of Nb2O5 2. 低温固态反应 A) SEM image of the as-prepared silver nanowires. B) Image A) with higher magnification. 3 水热合成法 4. 气相法Vapor phase growth of nanowires Vapor phase growth is extensively used for producing nanowires. Starting with the simple evaporation technique in an appropriate atmosphere to produce elemental or oxide nanowire