燃烧法制备硼酸镁纳米晶体研究分析.docVIP

燃烧法制备硼酸镁纳米晶体的研究 摘 要 燃烧法合成硼酸镁纳米晶体的技术是以六水硝酸镁（Mg(NO3)2·6H2O）、硼酸（BH3BO3）作为还原剂，再分别以柠檬酸、柠檬酸铵为燃烧剂，将还原剂与燃烧剂加热至自蔓延燃烧后，再使它们在500 ℃～1000 ℃的环境下煅烧5个小时，将会得到蓬松的粉末状产物，即为硼酸镁纳米晶体。 综述了我国硼酸镁生产的主要发展现状；介绍了该产品的应用领域及前景；指出了国内外市场的销售情况。 一、制备纳米级硼酸镁。称取一定量的普通六水硝酸镁和硼酸，分别放入两个分别装有柠檬酸铵和柠檬酸的干锅中，并用水溶解，不断的搅拌，最终经焙烧制得蓬松的泡沫状纳米硼酸镁。 二、以XRD分析手段进行表征，系统考察焙烧温度工艺参数对最终产物的影响，确定最佳的工艺条件。 三、实验结果表明，在适宜的操作条件下，用柠檬酸铵和柠檬酸为燃烧剂，均可以获得较好的纳米硼酸镁。 结果表明：燃烧法可以制备纳米硼酸镁，具有简单，快速，便宜的优点。 关键词：燃烧合成；纳米硼酸镁；燃烧剂；表征 Abstract Combustion Synthesis of magnesium borate nanocrystals, borate （BH3BO3）, Magnesium nitrate hexahydrate （Mg(NO3)2·6H2O）as a reducing agent, respectively, ammonium citrate, citric acid as a combustion agent, heated to a self-propagating combustion andcalcined at 500 ℃ ~ 1000 ℃ for 5 hours, fluffy powder-like product, that is, magnesium borate nanocrystals. Reviewed the development status of Chinas production of magnesium borate; applications and prospects of the product; pointed out that the sales of domestic and foreign markets A.Preparation of nanometer magnesium borate. Weigh a certain amount of ordinary Magnesium nitrate hexahydrate and boric acid were placed in two equipped with Griddle ammonium citrate and citric acid, and dissolved in water, constantly stirring final calcined fluffy foam-like nano-magnesium borate. Two were characterized by XRD analysis tools, the system examines the calcination time, calcination temperature on the composition and particle size of the final product, to determine the optimum process conditions. The experimental results show that under appropriate operating conditions, ammonium citrate and citric acid as a combustion agent can get a better nanometer magnesium borate. The results showed that: the combustion method to prepare nano-boric acid and magnesium, with the advantages of simple, fast, cheap. Key words: Combustion Synthesis；Nanometer magnesium borate；Burning agent；Characterization 目录 摘 要 I Abstract II 前 言 1 1文献综述 3 1.1纳米材料的研究 3 1.1.1纳米材料的定义 3 1.1.2纳米材料的分类及应用 3 1.1.3