钛渣电铝热还原一步合成ti-al-xfe-ysi多元合金热力学分析.docVIP

doi：10.3969/j.issn.1007-7545.2016.07.015 钛渣电铝热还原一步合成Ti-Al-xFe-ySi多元合金热力学分析 李军1,2，鲁雄刚1，杨绍利2，李重河1，吴恩辉2，侯静2，黄平2，李彬彬2，王涛2 (1.上海大学 省部共建高品质特殊钢冶金与制备国家重点实验室，上海200072； 2.攀枝花学院 攀西科技创新中心，四川攀枝花 617000) 摘要：从理论上分析了钛渣铝热还原制备Ti-Al-xFe-ySi多元合金的可行性，计算并分析了钛渣中金属氧化物与铝还原过程中可能的化学反应，讨论了钛渣中氧化物还原反应顺序的优先程度。结果表明，钛渣铝热还原制备钛铝基多元合金是可行的。从热力学分析了制备的合金中可能出现的二元合金相，主要为Ti5Si3、TiAl3和TiFe，其中Ti5Si3最易生成，研究结果较好地满足了热力学分析结果，制备的合金主要物相为Al2.68Mn0.32Ti和Al3Ti0.75Fe0.25，还有少量的TiFe和Ti3SiC2相。 关键词：钛渣；铝热还原；热力学；Ti-Al-xFe-ySi合金 中图分类号：TG146.23 文献标志码：A 文章编号：1007-7545（2016）07-0000-00 Thermodynamic Analysis on One-step Synthesis Ti-Al-xFe-ySi Multielement Alloy by Aluminothermic Reduction LI Jun1,2, LU Xiong-gang1, YANG Shao-li2, LI Chong-he1, WU En-hui2, HOU Jing2, HUANG Ping2, LI Bin-bin2, WANG Tao2 （1. National Key Laboratory of High-quality Special Steel Metallurgy and Preparation by the Province and the Ministry, Shanghai University, Shanghai 200072, China; 2. Panxi Scientific and Technological Innovation Center, Panzhihua University, Panzhihua 617000, Sichuan, China). Abstract: The feasibility to produce Ti-Al-xFe-ySi mutielement alloy from titanium slag by aluminothermic reduction was theoretically analyzed. Possible chemical reactions between metallic oxide in titanium slag and aluminum were calculated and analyzed. The priority reduction degree of metallic oxide was discussed. The results show that it is feasible to produce Ti-Al-xFe-ySi mutielement alloy from titanium slag by aluminothermic reduction. Main binary alloy phase presents as Ti5Si3, TiAl3, and TiFe from thermodynamics analysis and validated by experiments. Main phases of prepared alloy include Al2.68Mn0.32Ti and Al3Ti0.75Fe0.25, and a small amount of TiFe and Ti3SiC2. Key words: titanium slag; aluminothermic reduction; thermodynamics; Ti-Al-xFe-ySi alloy  中国是钛资源大国，攀西地区钛资源量居世界第一位[1]。攀枝花地区已经形成了钛精矿—钛渣—高钛渣—钛白粉—海绵钛全产业链生产流程。目前我国钛渣生产整体技术装备水平有可能形成30～40万t钛渣生产能力，其中含TiO2~75%的钛渣主要应用在硫酸法钛白领域。攀枝花钛原料生产的钛渣钙镁含量高，难以直接应用于氯化法钛白，而硫酸法生产钛白粉的质量较差，难以应用在高端领域。所以开辟钛渣的新应用途径具有现实意义。