魏加杰GN-nZVI对Cu(II)吸附论文最新5.19概述.doc

吉林师范大学环境科学与工程学院毕业论文  PAGE \* ROMAN III GN-nZVI处理含铜废水的研究 ?魏加杰 (吉林师范大学环境科学与工程学院11级3班 吉林四平136000) 指导教师：滕洪辉（副教授） 摘要：石墨烯是一种备受关注新型材料，其优异的性能为科学的发展带来了非常瞩目的影响。本实验将石墨烯与FeSO4.7H2O(七水硫酸亚铁)结合，以硼氢化钠为还原剂，生成复合材料石墨烯纳米铁（GN-nZVI），以含铜废水为研究对象，对其吸附性能进行分析研究。 研究结果表明，GN-nZVI对Cu(Ⅱ)去除的最佳pH为中性，此时废水中铜的处理效果明显而且相对稳定。Cu(Ⅱ)的去除率随GN-nZVI投加量和反应温度升高而升高，随初始浓度升高而降低。通过动力学分析，GN-nZVI对铜离子的吸附过程符合二级动力学拟合方程。此外，其F方程中的n＞1，表明是化学吸附过程，同样证明铜离子的去除与纳米铁的还原性能有关。通过TEM和SEM表征分析，表明了本实验GN-nZVI的制备方法能够使nZVI较均匀的分布在GN片层上。在水浴恒温超声器中303 K条件下GN-nZVI对Cu( = 2 \* ROMAN II)的最大吸附量达到609.567 mgg-1，效果非常好。同时，该实验对热力学参数(吉布斯自由能(△Go)，标准焓的变化(△Ho)，标准熵的变化(△So))进行了评估，表明该过程是放热、熵增大并且自发吸附过程。研究表明，GN-nZVI对废水中Cu( = 2 \* ROMAN II)去除具有很好的应用前景，也为未来石墨烯复合材料的研究提供基础数据和理论支持。 关键词：石墨烯; 纳米铁; 制备; 吸附; 动力学; 热力学。 Remove of Cu( = 2 \* ROMAN II) from Wastewater by GN-nZVI Wei Jiajie (Class3Crade11 in College of Environmental  HYPERLINK app:ds:science \t Science And Engineering, Jilin Normal University, Jilin Siping 136000) Directive teacher : Teng Hong-hui (Associate professor ) Abstract: In recent years, carbon nanotube is a high-profile and new materials, brought very great influence to the development of science. This experiment study is based on the properties of graphene preparation of nanometer materials , the adsorption of heavy metal copper. This experiment is mainly using graphene and FeSO4·7H2O (seven water ferrous sulfate) combined to generate designed. The GN - nZVI (graphene nano iron) is using the adsorption effect of grapheme nano materials to deal with wastewater containing copper. With the result of the experiment were analyzed, and designed. The GN - nZVI for Cu (Ⅱ) to remove the best pH value of 6.00, when the concentration of copper in the wastewater treatment effect is obvious and relatively stable, The removal rate of Cu(Ⅱ) with designed. The GN - nZVI dosing quantity and reaction temperature rises, with lower initial concentration. Finally, the optimal conditions in