日本电子顺磁共振波谱用户.ppt

Some ESR Experimental Results in our Laboratory ;Some interesting examples: ;Green line: intermediate state;①;Cube ;Octahedron;Research on Giant Magnetoresistance materials by ESR;Angular Rotation Experiments:;Part 1. In situ Variable Temperature ESR Characterization of Thermodynamics of Singly-bonded C60 Fullerene Dimer ;Synthesis experimental section: Chlorobenzene, 135℃, Mn(OAc)3, Ar, product yield ~88%;Fig. X-ray crystal structure of the predominant component (the meso isomer) of 2a. Thermal ellipsoids are drawn at 50% probability level.;The reversible dissociation of the (C60)2-(P(O)(OMe)2)2 dimer at 373K even to higher ;The continuous-wave (cw) in situ ESR measurements were performed on a JES-FA200 X-band (9.087 GHz, JEOL) ESR spectrometer equipped with a cavity which is capable of varying the temperature from 105 K to the maximum of 473 K. ;Figure 1. Experimental (black) and simulated (red) EPR spectra of the formed monomer ●C60P(O)(OMe)2 radical dissociated from dimer in ODCB at 373K;Temperature dependence Experiments:;;I is the EPR signal amplitude, I0 the maximum amplitude, and C0 the concentration of the original dimer before the heating treatment. ;ΔH0 ~ -[slope]×R;;Part 2. Very High Temperature ESR Characterization of Solid Superacid SO42-/TiO2 ;哈梅特(酸度)标度;SO42-/TiO2 Structure and acidity:;In situ ESR measurements were performed on a JES-FA200 X-band spectrometer (9.087 GHz, JEOL) equipped with an ES-HTXA high-temperature cavity, which is capable of varying the temperature from room temperature (293 K) to the maximum of 873 K. The samples in the standard EPR tubes were heated by the nitrogen (99.9%) gas flow with a heating rate of 1–100 K min-1.;b Simulation (bottom) on the EPR experimental spectrum (top) of the 3d1 Ti3+ ions with the axial symmetric g values (gx = gy = g∥ = 1.994), where the gz= g⊥, generally 1.960 (see the main text), was not resolved in the present higher temperature measurements.;Fig.a In situ