塔河原油外输管线腐蚀机理研究.docVIP

单位代码：10615 西 南 石 油 大 学 工程硕士学位论文 论文题目：塔河原油外输管线腐蚀机理研究 摘 要 塔河油田自1997年投入开发以来，已建原油处理规模能力530×104t/a，建成联合站3座，重质原油外输首站及末站各1座，原油外输管线179 km，满足了油田生产的需要。此管线自建成投产以来未进行过有关重质原油外输管道内腐蚀速率方面的试验，对于管线的腐蚀状况和腐蚀机理不是十分清楚。 本文采用实验室挂片法，分析了不同温度、时间、含水量等因素对外输管线的腐蚀影响规律，利用电子显微扫描、X射线衍射及电子能谱、俄歇电子能谱（AES）分析等方法完成了腐蚀形态、特征和形成机理分析，腐蚀产物主要成分为Fe、S、O、CCl，主要为Fe2O3同时含有一定量的FeS、NaCl。同时采用CORR-CP失重挂片装置，利用该式可以预测不同时间下管道腐蚀速率和腐蚀程度。 根据实验研究和腐蚀影响因素分析结果，在合理控制运行工况参数的前提下，针对性地提出了缓蚀剂＋电阻探针的腐蚀缓解及控制措施，缓蚀剂的缓蚀率在85%以上能有效降低管道腐蚀速率，保证了管线的安全运行和生产。 关键词：重质原油；腐蚀机理；腐蚀形态；腐蚀速率；缓蚀剂Abstract Tahe Oilfield has been devoted to its development since 1997, has built the scale of crude oil processing capacity of 530 × 104t / a, with three joint stations , one first and terminal station and 179 km long distance pipeline , to meet the oil production. Since the completion of this pipeline has not been put into the heavy crude oil transmission pipeline corrosion rate outside the pilot area for the pipeline corrosion and corrosion mechanisms are not very clear. In this paper, laboratory weightlessness experimenthanging, analysis of different temperature, time, water content of external factors such as corrosion of pipelines influence of the use of scanning electron microscopy, X-ray diffraction and electron spectroscopy, Auger electron spectroscopy (AES) analysis methods such as the completion of the corrosion morphology, characteristics and formation mechanism analysis of the corrosion products mainly composed of Fe, S, O, C, Cl, mainly Fe2O3 also contain a certain amount of FeS, NaCl. At the same time using CORR-CP weightlessness hanging piece installed in 705, the first stop and triple hanging piece for an online weight loss experiment to determine the 705 stations, the first stop, triple the corrosion rate. Using non-linear regression method to establish the existing conditions under the conditions of the average corrosion rate prediction equation , using the type can be predicted under different time and the corrosion rate of pipeline corr