ZnO纳米结构的气相输运合成讲述.ppt

Vapor Transport Synthesis of ZnO Nanostructures Members: S梁 艳 S尚双银 S李斯蓉 S钱 婧 S万玉腾 S杨 勇 Outline 01 02 03 Introduction Vapor Transport Synthesis Nanostructure formation mechanisms 04 Conclusion 1. Introduction ZnO versatile applications transparent electronics UV light emitters piezoelectric devices chemical sensors solar cells Preparation methods Vapor-phase transport process Chemical vapor deposition Arc discharge Laser ablation Solution a template-based method 2. Vapor Transport Synthesis the ways to generate Zn and oxygen vapor direct methods indirect methods Zn(g)+O2(g) ZnO Decomposition of ZnO heat up Zn powder under oxygen flow metal-organic vapor phase carbothermal method 2.1 direct methods 1. Decomposition of ZnO X. Y. Kong, Z. L. Wang, Nano. Lett. 3, 1625 (2003) ZnO ZnO Zn 2+ +O2- 1350°C 1350°C ~10-3Torr Ar deposited onto an alumina substrate 400?500 °C Ar —— limited to very high temperatures(~1400°C) 2.1 direct methods 2. heat up Zn powder under oxygen flow ——relative low growth temperature(500~700°C) ——the ratio between the Zn vapor pressure and oxygen pressure needs to be carefully controlled in order to obtain desired ZnO nanostructures P. Chang, Z. Fan, W. Tseng, D. Wang, W. Chiou, J. Hong, J. G. Lu, Chem. Mater. 16,5133 (2004) Fig 2.Schematic illustration of the CVD system with a horizontal quartz tube placed in a furnace. A small quartz vial inside the quartz tube is used to trap zinc vapor during the synthesis process. 2.2 indirect methods： 1. metal-organic vapor phase (MOCVD) S. Fujita, S.-W. Kim, M. Ueda, and S. Fujita, J. Cryst. Growth 272, 138 (2004) diethylzinc (DEZn) +N2O N2 700 °C，200 Torr ZnO Fig.3. SEM images showing the growth processes of ZnO on FIB-nanopatterned SiO2 substrate surface. The results are at (a) 40 s, (b)10 min, and (c) 15 min after starting the growth of ZnO 2. carbothermal method -——ZnO powder is mixed with graphit