毕业论文——何岩剖析.docVIP

2015 届毕业设计（论文） 题 目：过氧化物硫化体系对动态硫化EPDM/PP弹性体性能影响 专 业：高分子材料与工程 班 级： 高材1104 姓 名： 何岩 指导老师： 李怀栋 起讫日期：2014.12.22—2015.6.8 2015 年6 月摘要 本文研究了双螺杆挤出熔融共混过程中过氧化物硫化体系对动态硫化EPDM/PP（60/40wt%）热塑性弹性体的性能影响。实验表明，随着DCP用量的增加，试样的拉伸强度和凝胶含量都呈现先增大后减小的趋势，且当DCP用量为2%时的性能最佳。当采用DCP用量为2%时，随着螺杆转速的不断增加，试样的拉伸强度及凝胶含量呈现先增大后减小的趋势，结果发现，当螺杆转速为600rpm时，各性能达到最优。通过SEM分析表明，EPDM呈分散相、PP呈连续相。随着DCP用量的增加，分散相粒径越来越大；而螺杆转速的提高，EPDM分散的越均匀，且颗粒尺寸范围EPDM/PP 动态硫化 过氧化物 熔融共混 剪切应力Effect of peroxide curing system on the mechanical properties of dynamic vulcanization EPDM/PP thermoplastic elastomer Abstract In this paper, the effect of peroxide curing system on the thermoplastic elastomer of EPDM/PP (60/40wt%) in the melt blending process of twin screw extrusion was studied.Experimental results show that with the increasing of DCP, the tensile strength and gel content of the sample have shown a decreasing trend after the first increases, and the performance of the optimum when DCP dosage was 2%.When the dosage of DCP was 2%, the tensile strength and the gel content of the sample increased firstly and then decreased with the increase of the screw speed.It was found that when the screw speed of 600rpm,the respective optimal performance.Through SEM analysis, EPDM showed that the dispersed phase and PP were continuous phase.With the increase of DCP dosage, the particle size of the dispersed phase is increasing.The increase of screw speed, EPDM dispersed more uniformly, and the size of the particle is more stable.The best performance of the obtained is the gel content 93.61%, the tensile strength 16.91MPa, the elongation at break 549.22%, the permanent deformation 286.19% Key words: EPDM/PP; Dynamic Vulcanization; Peroxide; Melt blending; Shear stress 目录 摘要 I Abstract II 第一章 绪论 1 1.1 引言 1 1.2 研究背景 2 1.3 过氧化物硫化机理 2 1.4 国内外研究进展 4 1.5 本文研究的目的和内容 5 第二章 实验 6 2.1 实验部分 6 2.1.1 原料 6 2.1.2 仪器设备 6 2.1.3 试样制备 6 2.1.4 性能测试 7 2.1.5 试样凝胶含量的测定方法 7 第三章 结果与讨论 8 3.1 DCP用量对EPDM