Solutions to Exercises-Chapter 8-电化学基础.docVIP

Solutions to Excercises Chapter 8 电化学基础 Ⅰ. ?Fill in the blanks 1. Consider the reaction in acid: Cr2O72- aq +? Sn2+ aq Cr3+ aq +Sn4+ aq Balance the equation in acid: . In this reaction, was oxidized; was the oxidizing agent. Cr2O72- aq +? 3Sn2+ aq +14H+2Cr3+ aq +3Sn4+ aq +7H2O; Sn2+; Cr2O72- 2. If the primary cell can be designed by the redox reaction : Fe2++Ag+Fe3++Ag, the equation for the anode halfreacton is ; the notation of the cell is . Fe2+-e-Fe3+; - Pt| Fe2+, Fe3+||Ag+ |Ag + 3. Consider the cell: - Zn|ZnSO4 c ||AgNO3 c |Ag + . The cell emf will when we increase the