2催化化学-吸附作用剖析.pptVIP

第二章 吸附作用 第二章 吸附作用 第二章 吸附作用 Example Heterogeneous Catalytic Reaction Process The long journey for reactant molecules to j. travel within gas phase k. cross gas-liquid phase boundary l. travel within liquid phase/stagnant layer m. cross liquid-solid phase boundary n. reach outer surface of solid o. diffuse within pore p. arrive at reaction site q. be adsorbed on the site and activated r. react with other reactant molecules, either being adsorbed on the same/neighbour sites or approaching from surface above Product molecules must follow the same track in the reverse direction to ret